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2,2′:5′,2′′-Terthiophene

ALDRICH/311073 - 99%

Synonym: α-Terthienyl; 2,5-Di(2-thienyl)thiophene

CAS Number: 1081-34-1
Empirical Formula (Hill Notation): C12H8S3
Molecular Weight: 248.39
MDL Number: MFCD00012167
Linear Formula: C12H8S3
Product Type: Chemical

Catalog Number PKG Qty. Price Quantity
45-311073-1G 1 g
$242.00
1/EA
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This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 311073-1G

 

assay 99%
InChI 1S/C12H8S3/c1-3-9(13-7-1)11-5-6-12(15-11)10-4-2-8-14-10/h1-8H
InChI key KXSFECAJUBPPFE-UHFFFAOYSA-N
mp 93-95 °C (lit.)
SMILES string c1csc(c1)-c2ccc(s2)-c3cccs3
Application: 3T can be combined with 3,4-ethylenedioxythiophene (EDOT) in a tetrabutylammonium perchlorate solution for use as an electrochromic copolymer for a wide range of applications like photovoltaics and polymer light emitting diodes (LEDs). It can also be used to form metal-organic based thin films with metals like aluminum, silver, and calcium which can potentially be used for optoelectronics based applications.
Application: Electrochemical copolymerization of carbazole and TTh in sodium perchlorate/acetonitrile was reported. Electrochromic copolymer based on TTh and 3, 4-ethylenedioxythiophene has been reported. TTh acts as a monomer precursor for polythiophene and as a dopant for polycarbonate. It may function as a photosensitizer.
General description: 2,2′:5′,2′′-Terthiophene (3T) is a tri-thiophene based low band conductive polymer that is prepared by reacting 2,5-dibromothiophene and thienylmagnesium bromide in the presence of nickel catalyst.
General description: 2,2′:5′,2′′-Terthiophene (TTh) may be prepared by nickel catalysed coupling reaction of grignard′s reagent derived from 2-bromothiophene and magnesium. It generates singlet oxygen. In nature, it is found in the floral extract of Tagetes minuta and Echinops grijisii. It is known to be toxic to mosquitoes. It also exihibits antifungal activity.
Packaging: 1 g in glass bottle
Packaging: 250 mg in glass bottle
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity 99%
mp 93-95 °C (lit.)
UNSPSC 12352103

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