Perchloric acid
ALDRICH/311421 - 70%, 99.999% trace metals basis
Synonym: PCA
CAS Number: 7601-90-3
Empirical Formula (Hill Notation): HClO4
Molecular Weight: 100.46
MDL Number: MFCD00011325
Linear Formula: HClO4
Product Type: Chemical
| assay | 70% |
| 99.999% trace metals basis | |
| bp | ca.203 °C/at 1.013 hPa |
| cation traces | Al: ≤0.3 ppm |
| Ca: ≤0.3 ppm | |
| Fe: ≤ 0.1 ppm | |
| Na: 3.1 ppm | |
| Zn: ≤ 0.1 ppm | |
| concentration | ≥70-- < 90% |
| density | 1.664 g/mL at 25 °C |
| form | liquid |
| InChI | 1S/ClHO4/c2-1(3,4)5/h(H,2 |
| InChI key | VLTRZXGMWDSKGL-UHFFFAOYSA |
| mp | 18 °C |
| Quality Level | 100 ![]() |
| reaction suitability | reagent type: oxidant |
| SMILES string | OCl(=O)(=O)=O |
| solubility | water: miscible (completely) |
| vapor pressure | 6.8 mmHg ( 25 °C) |
| Application: | Perchloric acid (HClO4) can be used in the preparation of: • Silica supported perchloric acid (HClO4-SiO2) which is used as a catalyst in geminal diacylation of aldehydes, synthesis of amidoalkyl naphthols, primary carbamates, and tetrasubstituted imidazoles. • Alumina supported perchloric acid (Al2O3-HClO4), which is used as a catalyst in the synthesis of • Fe3O4@SiO2-HClO4 catalyst, which is used in the synthesis of 1,4-dihydropyridine derivatives. |
| Application: | Perchloric acid can be used as: • A reaction medium in oxidation reactions. • A reagent for the preparation of fluorinated polymer electrolytes using poly (vinylidenefluoride-cohex • A dopant in the preparation of perchloric acid-functionalized polyaniline (HClO4/PANI) catalyst for the synthesis of 2-substituted benzothiazoles by condensation reaction between o-aminothiophenol with aldehydes. |
| Packaging: | 1 L in glass bottle |
| Packaging: | 50, 250 mL in glass bottle |
| Symbol | ![]() ![]() ![]() GHS03,GHS05,GHS07,GHS08 |
| Signal word | Danger |
| Hazard statements | H271 - H290 - H302 - H314 - H373 |
| Precautionary statements | P210 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338 - P314 |
| Hazard Codes | O,C |
| Risk Statements | 5-8-22-35 |
| Safety Statements | 26-36/37/39-45 |
| RIDADR | UN 1873 8(5.1) / PGI |
| WGK Germany | WGK 1 |
| Purity | 70%; 99.999% trace metals basis |
| bp | ca.203 °C/at 1.013 hPa |
| mp | 18 °C |
| Density | 1.664 g/mL at 25 °C |
| UNSPSC | 12352302 |





