(+)-DIP-Chloride™
ALDRICH/317012 - 90-105% (approx.)
Synonym: (+)
CAS Number: 112246-73-8
Empirical Formula (Hill Notation): C20H34BCl
Molecular Weight: 320.75
MDL Number: MFCD01317328
Linear Formula: C20H34BCl
Product Type: Chemical
assay | 90-105% (approx.) |
form | solid |
InChI | 1S/C20H34BCl/c1-11-15-7-1 |
InChI key | PSEHHVRCDVOTID-NAVXHOJHSA |
mp | 53-55 °C (lit.) |
SMILES string | C[C@@H]1[C@H](C[C@H]2C[C@ |
Application: | Both (+)- and (-)-DIP-chloride are used for asymmetric reduction of prochiral ketones and for the preparation of β-amino alcohols. |
Application: | Excellent reagent for asymmetric reductions. |
Application: | For a short paper on the preparation of DIP halides and their use in stereoselective reductions see ACS Symp. Ser. 641, 84-97 (1996). |
Legal Information: | DIP-Chloride is a trademark of Sigma-Aldrich Co. LLC |
Packaging: | 5, 25 g in glass bottle |
Symbol | GHS05 |
Signal word | Danger |
Hazard statements | H314 |
Precautionary statements | P280 - P305 + P351 + P338 - P310 |
Hazard Codes | C |
Risk Statements | 34-37 |
Safety Statements | 26-36/37/39-45 |
RIDADR | UN 3261 8 / PGII |
WGK Germany | WGK 3 |
Flash Point(F) | 230.0 °F - closed cup |
Flash Point(C) | 110 °C - closed cup |
Purity | 90-105% (approx.) |
mp | 53-55 °C (lit.) |
UNSPSC | 12352001 |