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(+)-B-Methoxydiisopinocampheylborane

ALDRICH/317039

Synonym: (+)-Diisopinocampheylmethoxyborane

CAS Number: 99438-28-5
Empirical Formula (Hill Notation): C21H37BO
Molecular Weight: 316.33
MDL Number: MFCD21332906
Linear Formula: C21H37BO
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-317039-5G 5 g
 $149.00
1/EA		 Add To Favorites
45-317039-25G 25 g
 $274.00
1/EA		 Add To Favorites
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 317039-100G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 317039-25G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 317039-5G

 

form solid
InChI 1S/C21H37BO/c1-12-16-8-14(20(16,3)4)10-18(12)22(23-7)19-11-15-9-17(13(19)2)21(15,5)6/h12-19H,8-11H2,1-7H3/t12-,13-,14+,15+,16-,17-,18-,19-/m0/s1
InChI key IAQXEQYLQNNXJC-JPDDNCELSA-N
SMILES string COB([C@H]1CC2CC([C@@H]1C)C2(C)C)[C@H]3CC4CC([C@@H]3C)C4(C)C
Application: Both (+)- and (-)-forms are precursors to B-allyldiisopinocampheylborane derivatives, which are subsequently reacted with aldehydes to give homoallylic alcohols and β-amino alcohols of high enantiomeric excess.
Application: Reactant involved in:
• Oxidative cyclization and alkylation for synthesis of ionomycin
• Intramolecular conjugate addition for tetrahydropyran synthesis
• Aldol addition and Suzuki coupling reactions
• Allylation
• Synthesis of alkanols
Packaging: 5, 25, 100 g in glass bottle
UNSPSC 12352001

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