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(−)-B-Methoxydiisopinocampheylborane

ALDRICH/317047

Synonym: (−)-Diisopinocampheylmethoxyborane

CAS Number: 85134-98-1
Empirical Formula (Hill Notation): C21H37BO
Molecular Weight: 316.33
MDL Number: MFCD00074809
Linear Formula: C21H37BO
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-317047-25G 25 g
 $439.00
1/EA		 Add To Favorites
45-317047-100G 100 g
 $673.00
1/EA		 Add To Favorites
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 317047-100G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 317047-25G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 317047-5G

 

form solid
InChI 1S/C21H37BO/c1-12-16-8-14(20(16,3)4)10-18(12)22(23-7)19-11-15-9-17(13(19)2)21(15,5)6/h12-19H,8-11H2,1-7H3/t12-,13-,14-,15-,16+,17+,18-,19-/m0/s1
InChI key IAQXEQYLQNNXJC-BAMGFKBFSA-N
SMILES string COB([C@H]1CC2CC([C@@H]1C)C2(C)C)[C@H]3CC4CC([C@@H]3C)C4(C)C
Application: Reactant involved in organic synthesis reactions such as:
• Double allylboration for synthesis of fragments of tetrafibricin
• Anticancer cytotoxic monorhizopodin synthesis
• Annulation of cyclic allylsilanes
• Asymmetric synthesis of β-amino-α-hydroxy acid taxol side chain analogs
General description: B-Methoxydiisopinocampheylborane (Ipc2BOMe) is an organoborane compound, which is prepared from excess α-pinene, borane dimethylsulfide, and methanol via the formation of an intermediate diisocampheylborane. Ipc2BOMe is used as a versatile reagent for the construction of C-C bonds in asymmetric synthesis.
Packaging: 5, 25, 100 g in glass bottle
UNSPSC 12352001

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