Methyl 2-acetamidoacrylate
ALDRICH/317519 - 98%
CAS Number: 35356-70-8
Empirical Formula (Hill Notation): C6H9NO3
Molecular Weight: 143.14
MDL Number: MFCD00013394
Linear Formula: H2C=C(NHCOCH3)CO2CH3
Product Type: Chemical
assay | 98% |
bp | 104 °C/8 mmHg (lit.) |
InChI | 1S/C6H9NO3/c1-4(6(9)10-3) |
InChI key | SMWNFFKPVLVOQQ-UHFFFAOYSA |
mp | 50-52 °C (lit.) |
SMILES string | COC(=O)C(=C)NC(C)=O |
Application: | Methyl 2-acetamidoacrylate can undergo [2+2] cycloaddition (Michael–Dieckmann-type reaction) with ketene diethyl acetal to yield the cyclobutane core. It may be used in rhodium-catalyzed 2-alkenylpyrrole formation. |
General description: | Conjugated addition of secondary amines, imidazole and pyrazole to methyl 2 methyl 2-acetamidoacrylate in the presence of a catalyst results in the formation of β-Dialkylamino-α-alanine and β-(N-heteroaryl)-α-alanine derivatives. Methyl-2-acetamidoacrylat |
General description: | Methyl ester of 2-acetamidoacrylate . methyl 2-acetamidoacrylate (Me-2-AA) is a di-unsaturated α-amino acid derivative. methyl-2-acetamidoacrylat |
Packaging: | 1, 5 g in glass bottle |
Symbol | GHS07 |
Signal word | Warning |
Hazard statements | H315 - H319 - H335 |
Precautionary statements | P302 + P352 - P305 + P351 + P338 |
Hazard Codes | Xi |
Risk Statements | 36/37/38 |
Safety Statements | 26-37/39 |
RIDADR | NONH for all modes of transport |
WGK Germany | WGK 3 |
Flash Point(F) | 235.4 °F - closed cup |
Flash Point(C) | 113 °C - closed cup |
Purity | 98% |
bp | 104 °C/8 mmHg (lit.) |
mp | 50-52 °C (lit.) |
UNSPSC | 12162002 |