Methyl 2-acetamidoacrylate

ALDRICH/317519 - 98%

CAS Number: 35356-70-8
Empirical Formula (Hill Notation): C₆H₉NO₃
Molecular Weight: 143.14
MDL Number: MFCD00013394
Linear Formula: H₂C=C(NHCOCH₃)CO₂CH₃
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-317519-5G	5 g	$303.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	98%
bp	104 °C/8 mmHg (lit.)
InChI	1S/C6H9NO3/c1-4(6(9)10-3)7-5(2)8/h1H2,2-3H3,(H,7,8)
InChI key	SMWNFFKPVLVOQQ-UHFFFAOYSA-N
mp	50-52 °C (lit.)
Quality Level	100
SMILES string	COC(=O)C(=C)NC(C)=O

Application:	Methyl 2-acetamidoacrylate can undergo [2+2] cycloaddition (Michael–Dieckmann-type reaction) with ketene diethyl acetal to yield the cyclobutane core. It may be used in rhodium-catalyzed 2-alkenylpyrrole formation.
General description:	Conjugated addition of secondary amines, imidazole and pyrazole to methyl 2 methyl 2-acetamidoacrylate in the presence of a catalyst results in the formation of β-Dialkylamino-α-alanine and β-(N-heteroaryl)-α-alanine derivatives. Methyl-2-acetamidoacrylate (M2AA) is an anti-inflammatory agent. The catalytic reaction of methyl 2-acetamidoacrylate with Grignard’s reagents affords α-amino esters. M2AA can form thermosensitive copolymers with methyl acrylate.
General description:	Methyl ester of 2-acetamidoacrylate . methyl 2-acetamidoacrylate (Me-2-AA) is a di-unsaturated α-amino acid derivative. methyl-2-acetamidoacrylate exihibits anti -inflammatory properties, it is very effective against lipopolysaccharide (LPS)- induced nitric oxide production by RAW 264.
Packaging:	1, 5 g in glass bottle

Symbol	GHS07
Signal word	Warning
Hazard statements	H315 - H319 - H335
Precautionary statements	P302 + P352 - P305 + P351 + P338
Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-37/39
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	235.4 °F - closed cup
Flash Point(C)	113 °C - closed cup

Purity	98%
bp	104 °C/8 mmHg (lit.)
mp	50-52 °C (lit.)
UNSPSC	12162002

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