2-Chloro-1,3,2-benzodioxaphosphorin-4-one
ALDRICH/324124 - 95%
Synonym: SalPCl; Salicyl chlorophosphite
CAS Number: 5381-99-7
Empirical Formula (Hill Notation): C7H4ClO3P
Molecular Weight: 202.53
MDL Number: MFCD00013353
Linear Formula: C7H4ClO3P
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 324124-5G
| assay | 95% |
| bp | 127-128 °C/11 mmHg (lit.) |
| form | solid |
| functional group | phosphine |
| InChI | 1S/C7H4ClO3P/c8-12-10-6-4 |
| InChI key | BVOITXUNGDUXRW-UHFFFAOYSA |
| mp | 36-40 °C (lit.) |
| Quality Level | 200  |
| reaction suitability | reaction type: Buchwald-Hartwig Cross Coupling Reaction |
| reaction type: Heck Reaction | |
| reaction type: Hiyama Coupling | |
| reaction type: Negishi Coupling | |
| reaction type: Sonogashira Coupling | |
| reaction type: Stille Coupling | |
| reaction type: Suzuki-Miyaura Coupling | |
| reagent type: ligand | |
| SMILES string | ClP1OC(=O)c2ccccc2O1 |
| storage temp. | 2-8°C |
| Application: | 2-Chloro-1,3,2-benzodioxa • In the phosphorylation and phosphitylation of alcohols. • In the formation of H-phosphonates which are commonly utilized in the synthesis of nucleotides. • To synthesize nucleoside triphosphates by treating with acyl protected nucleoside. |
| Packaging: | 5, 25 g in glass bottle |
| Symbol |  GHS05 |
| Signal word | Danger |
| Hazard statements | H314 |
| Precautionary statements | P280 - P305 + P351 + P338 - P310 |
| Hazard Codes | C |
| Risk Statements | 14-34 |
| Safety Statements | 26-36/37/39-43-45 |
| RIDADR | UN 3261 8 / PGI |
| WGK Germany | WGK 3 |
| Flash Point(F) | 235.4 °F - closed cup |
| Flash Point(C) | 113 °C - closed cup |
| Supplemental Hazard Statements | EUH014 |
| Purity | 95% |
| bp | 127-128 °C/11 mmHg (lit.) |
| mp | 36-40 °C (lit.) |
| Storage Temp. | 2-8°C |
| UNSPSC | 12352005 |