Potassium trimethylsilanolate
ALDRICH/324868 - 90%, technical grade
Synonym: Trimethylsilanol potassium salt
CAS Number: 10519-96-7
Empirical Formula (Hill Notation): C3H9KOSi
Molecular Weight: 128.29
EC Number: 234-062-7
MDL Number: MFCD00013421
Linear Formula: (CH3)3SiOK
Product Type: Chemical
assay | 90% |
grade | technical grade |
InChI | 1S/C3H9OSi.K/c1-5(2,3)4;/ |
InChI key | LBKJNHPKYFYCLL-UHFFFAOYSA |
mp | 135-138 °C (lit.) |
Quality Level | 200 |
SMILES string | [K+].C[Si](C)(C)[O-] |
Application: | Potassium trimethylsilanolate can be used as a reagent in the: • Hydrolysis of nitriles to primary amides. • Conversion of esters to carboxylic acids, and dialkyl phosphonates to their monoalkyl phosphonates. • Synthesis of E-alkenes, and nitrocefin. It can also be used as a coupling promoter in cross-coupling reaction of aliphatic alkynylsilanols with aryl iodides. |
Packaging: | 1 kg in glass bottle |
Packaging: | 25, 100 g in glass bottle |
Symbol | GHS05 |
Signal word | Danger |
Hazard statements | H314 |
Precautionary statements | P303 + P361 + P353 - P305 + P351 + P338 |
Hazard Codes | C |
Risk Statements | 34 |
Safety Statements | 26-36/37/39-45 |
RIDADR | UN 3263 8 / PGII |
WGK Germany | WGK 3 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Purity | 90% |
mp | 135-138 °C (lit.) |
UNSPSC | 12352302 |