Pentacarbonylchlororhenium(I)
ALDRICH/327611 - 98%
Synonym: Rhenium(I) pentacarbonyl chloride
CAS Number: 14099-01-5
Empirical Formula (Hill Notation): C5ClO5Re
Molecular Weight: 361.71
EC Number: 237-948-1
MDL Number: MFCD00013296
Linear Formula: Re(CO)5Cl
Product Type: Chemical
assay | 98% |
InChI | 1S/5CO.ClH.Re/c5*1-2;;/h; |
InChI key | JQUUAHKBIXPQAP-UHFFFAOYSA |
reaction suitability | core: rhenium |
reagent type: catalyst | |
SMILES string | Cl[Re].[C-]#[O+].[C-]#[O+ |
Application: | Used to study π-electron deficient complexes between tricarbonylhalorhenium and diimine ligands and also to prepare [3]-ferrocenophane complexes. Employed in preparation of a series of mixed-valence compounds of rhenium and iron these compounds find application in the study of charge-transfer processes. |
Other Notes: | For a review of organometallic complexes of rhenium, see Science of Synthesis. |
Packaging: | 1, 5 g in glass bottle |
Symbol | GHS06 |
Signal word | Danger |
Hazard statements | H301 + H311 + H331 - H315 - H319 - H335 |
Precautionary statements | P261 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P311 - P305 + P351 + P338 |
Hazard Codes | T |
Risk Statements | 23/24/25-36/37/38 |
Safety Statements | 26-28-36/37/39-45 |
RIDADR | UN 3288 6.1 / PGIII |
WGK Germany | WGK 3 |
Purity | 98% |
UNSPSC | 12161600 |