[1,2-Bis(diphenylphosphino)ethane]dichloronickel(II)

ALDRICH/328219

Synonym: 1,2-Ethylenebis(diphenylphosphine)nickel dichloride; Nickel 1,2-Bis(diphenylphosphino)ethane dichloride; [1,2-Bis(diphenylphosphino)ethane]nickel(II) chloride; dppeNiCl₂

CAS Number: 14647-23-5
Empirical Formula (Hill Notation): C₂₆H₂₄Cl₂NiP₂
Molecular Weight: 528.02
MDL Number: MFCD00013313
Linear Formula: [(C₆H₅)₂PCH₂CH₂P(C₆H₅)₂]NiCl₂
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-328219-1G	1 g	$36.40 1/EA	Add To Favorites
45-328219-5G	5 g	$112.00 1/EA	Add To Favorites
45-328219-25G	25 g	$325.00 1/EA	Add To Favorites

This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 328219-25G

Properties
Descriptions
Safety Info.
Basic Data

form	solid
InChI	1S/C26H24P2.2ClH.Ni/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2
InChI key	XXECWTBMGGXMKP-UHFFFAOYSA-L
mp	263-265 °C (lit.)
Quality Level	100
reaction suitability	core: nickel
	reagent type: catalyst
SMILES string	Cl[Ni]Cl.C(CP(c1ccccc1)c2ccccc2)P(c3ccccc3)c4ccccc4

Application:	Reactant involved in: • Kumada catalyst-transfer polycondensation • Oxidation of carboranyl phosphine ligands • Synthesis of nickel-iron dithiolato hydrides • Ullmann reactions - homocoupling reactions Co-catalyst for hydroformylation of alcohols for the synthesis of quaternary carbon centers Catalyst for Wacker-type intramolecular aerobic oxidative amination of alkenes
Packaging:	1, 5, 25 g in glass bottle

Symbol	GHS07,GHS08
Signal word	Danger
Hazard statements	H302 + H312 + H332 - H315 - H319 - H334 - H335 - H350
Precautionary statements	P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338 - P308 + P313
Hazard Codes	T
Risk Statements	45-20/21/22-36/37/38-42/43
Safety Statements	53-22-26-36-45
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

mp	263-265 °C (lit.)
UNSPSC	12161600

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