[1,2-Bis(diphenylphosphino)ethane]dichloronickel(II)
ALDRICH/328219
Synonym: 1,2-
CAS Number: 14647-23-5
Empirical Formula (Hill Notation): C26H24Cl2NiP2
Molecular Weight: 528.02
MDL Number: MFCD00013313
Linear Formula: [(C6H5)2PCH2CH2P(C6H5)2]NiCl2
Product Type: Chemical
form | solid |
InChI | 1S/C26H24P2.2ClH.Ni/c1-5- |
InChI key | XXECWTBMGGXMKP-UHFFFAOYSA |
mp | 263-265 °C (lit.) |
reaction suitability | core: nickel |
reagent type: catalyst | |
SMILES string | Cl[Ni]Cl.C(CP(c1ccccc1)c2 |
Application: | Reactant involved in: • Kumada catalyst-transfer polycondensation • Oxidation of carboranyl phosphine ligands • Synthesis of nickel-iron dithiolato hydrides • Ullmann reactions - homocoupling reactions Co-catalyst for hydroformylation of alcohols for the synthesis of quaternary carbon centers Catalyst for Wacker-type intramolecular aerobic oxidative amination of alkenes |
Packaging: | 1, 5, 25 g in glass bottle |
Symbol | GHS07,GHS08 |
Signal word | Danger |
Hazard statements | H302 + H312 + H332 - H315 - H319 - H334 - H335 - H350 |
Precautionary statements | P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338 - P308 + P313 |
Hazard Codes | T |
Risk Statements | 45-20/21/22-36/37/38-42/43 |
Safety Statements | 53-22-26-36-45 |
RIDADR | NONH for all modes of transport |
WGK Germany | WGK 3 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
mp | 263-265 °C (lit.) |
UNSPSC | 12161600 |