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Sodium trimethylsilanolate

ALDRICH/329576 - 95%

Synonym: Trimethylsilanol sodium salt

CAS Number: 18027-10-6
Empirical Formula (Hill Notation): C3H9NaOSi
Molecular Weight: 112.18
EC Number: 241-939-8
MDL Number: MFCD00013926
Linear Formula: (CH3)3SiONa
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-329576-25G 25 g
 $191.00
1/EA		 Add To Favorites
45-329576-100G 100 g
 $550.00
1/EA		 Add To Favorites
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 329576-100G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 329576-25G

 

assay 95%
form powder
InChI 1S/C3H9OSi.Na/c1-5(2,3)4;/h1-3H3;/q-1;+1
  [1S/C3H9OSi.Na/c1-5(2,3)4;/h1-3H3;/q-1;+1]
InChI key HSNUIYJWTSJUMS-UHFFFAOYSA-N
  [HSNUIYJWTSJUMS-UHFFFAOYSA-N]
mp 230 °C ((lit.))
  230 °C (dec.) (lit.)
Quality Level 100 
SMILES string [Na+].C[Si](C)(C)[O-]
  [[Na+].C[Si](C)(C)[O-]]
Application: Sodium trimethylsilanolate is used as a catalyst in the: • Synthesis of the rhodium silonate complex.
•  Silylation of methylphenylsilane with tert-butyldimethylsilanol to synthesize trisiloxanes.
General description: Sodium trimethylsilanolate is a versatile and very powerful reagent for the conversion of esters to carboxylic acids and the hydrolysis of nitriles to primary amides. It can be used as a starting material for the synthesis of metal silanolates via the salt metathesis and as a catalyst for the silylation of silanols with hydrosilanes.
Packaging: 25, 100 g in glass bottle
Symbol GHS05  GHS05
Signal word Danger
Hazard statements H314
Precautionary statements P280 - P305 + P351 + P338 - P310
Hazard Codes C
Risk Statements 34
Safety Statements 26-36/37/39-45
RIDADR UN 3263 8 / PGII
WGK Germany WGK 3
Flash Point(F) 230.0 °F - closed cup
Flash Point(C) 110 °C - closed cup
Purity 95%
mp 230 °C ((lit.)); 230 °C (dec.) (lit.)
UNSPSC 12352000

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