Phenylmagnesium bromide solution

ALDRICH/331376 - 1.0 M in THF

Synonym: PhMgBr solution

CAS Number: 100-58-3
Empirical Formula (Hill Notation): C₆H₅BrMg
Molecular Weight: 181.31
MDL Number: MFCD00000038
Linear Formula: C₆H₅MgBr
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-331376-4X25ML	25 mL	No Price
45-331376-50ML	50 mL	$63.50 1/EA		Add To Favorites
45-331376-100ML	100 mL	$73.40 1/EA		Add To Favorites
45-331376-800ML	800 mL	$183.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

concentration	1.0 M in THF
density	1.004 g/mL at 25 °C
InChI	1S/C6H5.BrH.Mg/c1-2-4-6-5-3-1;;/h1-5H;1H;/q;;+1/p-1
InChI key	ANRQGKOBLBYXFM-UHFFFAOYSA-M
Quality Level	200
reaction suitability	reaction type: Grignard Reaction
SMILES string	Br[Mg]c1ccccc1

Application:	Phenylmagnesium bromide (PhMgBr) solution is an organomagnesium reagent mainly used in Grignard reaction, which finds application as the key step in the synthesis of (S)-2(diphenylmethyl)pyrrolidine, a chiral solvating agent for the NMR analysis. PhMgBr can also undergo palladium-catalyzed Grignard coupling with alkyl chlorides to form the cross-coupled product in good yield.
Other Notes:	Storage below 25°C may cause crystallization. Warm gently to redissolve solid.
Packaging:	50, 100, 800 mL in Sure/Seal™

Symbol	GHS02,GHS05,GHS07,GHS08
Signal word	Danger
Hazard statements	H225 - H314 - H335 - H351
Precautionary statements	P210 - P260 - P280 - P305 + P351 + P338 - P370 + P378 - P403 + P235
Hazard Codes	F,C
Risk Statements	11-14-19-34-37-40
Safety Statements	9-16-26-33-36/37/39-45
RIDADR	UN 2924 8(3) / PGII
WGK Germany	WGK 3
Flash Point(F)	1.4 °F - closed cup
Flash Point(C)	-17 °C - closed cup
Supplemental Hazard Statements	EUH014 - EUH019

Density	1.004 g/mL at 25 °C
UNSPSC	12352103

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