Advanced Search



Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II)

ALDRICH/334995

Synonym: Carbonylchlorohydrotris(triphenylphosphine)ruthenium

CAS Number: 16971-33-8
Empirical Formula (Hill Notation): C55H46ClOP3Ru
Molecular Weight: 952.40
EC Number: 241-051-0
MDL Number: MFCD00049804
Linear Formula: [(C6H5)3P]3Ru(CO)(Cl)H
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-334995-1G 1 g
 $146.00
1/EA		 Add To Favorites
45-334995-5G 5 g
 $421.00
1/EA		 Add To Favorites
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 334995-1G

 

InChI 1S/3C18H15P.CO.ClH.Ru/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;/h3*1-15H;;1H;/q;;;;;+1/p-1
InChI key MVJRXTSUBHUUPN-UHFFFAOYSA-M
mp 204-206 °C (dec.) (lit.)
Quality Level 100 
reaction suitability core: ruthenium
  reagent type: catalyst
SMILES string Cl[Ru].[C-]#[O+].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
Application:
  • Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II): This ruthenium complex is used as a versatile catalyst for various reactions including hydrogenation, transfer hydrogenation, C-C bond-forming reactions, α-alkylation of ketones with primary alcohols, and as a precursor for pincer ruthenium carbonyl catalysts for hydrogenation. The complex is noted for its physical properties, such as decomposing above its melting point (204-206°C), and its solubility characteristics. It is very insoluble in water, ethanol, and DMSO, sparingly soluble in benzene and acetone, and slightly soluble in chloroform (Kuriyama, 2001 ).
General description: Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II) is a coordination compound commonly used as a catalyst in organic synthesis reactions such as hydrogenation, transfer hydrogenative C-C bond-forming reactions, transfer hydrogenation, and α-alkylation of ketones with primary alcohols. In addition, it is used as a precursor of pincer ruthenium carbonyl catalysts for hydrogenation.
Packaging: 1, 5 g in glass bottle
mp 204-206 °C (dec.) (lit.)
UNSPSC 12161600

The following items have been added to your cart:

Choose a favorite list for this item:
Catalog Number Description Price
$

Returns/Order support

Please fill out the form below if you want to request order support from Krackeler Scientific.


Quick Order

* Required


New Year Price Updates

We are currently working diligently to update our website pricing information for the New Year. If you place an order, you will be acknowledged with any corrected pricing. If you'd like the most current information sooner, please don't hesitate to drop us an email or give us a call and we'd be happy to assist. Thank you for your patience while we are updating.

800-334-7725
office@krackeler.com


Play Video

To Request a Quote

  1. Search or Browse for items and add to them to your Shopping Cart.
  2. Click the "Request Quote" button at the bottom of the Shopping Cart page.
  3. Fill out required fields.
  4. Optionally you can convert to standard checkout mode by choosing a payment type.
  5. Click "Request Quote" at the bottom of the page.

You will be contacted with a quote.

To Order From a Quote

  1. Register and login to the website.
  2. Receive a quote from your sales representative or customer service.
  3. Have your copy of the quote in hand.
  4. Visit our quote module to search for your quote.
Back to Top