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Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II)

ALDRICH/334995

Synonym: Carbonylchlorohydrotris(triphenylphosphine)ruthenium

CAS Number: 16971-33-8
Empirical Formula (Hill Notation): C55H46ClOP3Ru
Molecular Weight: 952.40
EC Number: 241-051-0
MDL Number: MFCD00049804
Linear Formula: [(C6H5)3P]3Ru(CO)(Cl)H
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-334995-1G 1 g
 $137.00
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45-334995-5G 5 g
 $395.00
1/EA		 Add To Favorites
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 334995-1G

 

InChI 1S/3C18H15P.CO.ClH.Ru/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;/h3*1-15H;;1H;/q;;;;;+1/p-1
InChI key MVJRXTSUBHUUPN-UHFFFAOYSA-M
mp 204-206 °C (dec.) (lit.)
reaction suitability core: ruthenium
  reagent type: catalyst
SMILES string Cl[Ru].[C-]#[O+].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
Application:
  • Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II): This ruthenium complex is used as a versatile catalyst for various reactions including hydrogenation, transfer hydrogenation, C-C bond-forming reactions, α-alkylation of ketones with primary alcohols, and as a precursor for pincer ruthenium carbonyl catalysts for hydrogenation. The complex is noted for its physical properties, such as decomposing above its melting point (204-206°C), and its solubility characteristics. It is very insoluble in water, ethanol, and DMSO, sparingly soluble in benzene and acetone, and slightly soluble in chloroform (Kuriyama, 2001 ).
General description: Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II) is a coordination compound commonly used as a catalyst in organic synthesis reactions such as hydrogenation, transfer hydrogenative C-C bond-forming reactions, transfer hydrogenation, and α-alkylation of ketones with primary alcohols. In addition, it is used as a precursor of pincer ruthenium carbonyl catalysts for hydrogenation.
Packaging: 1, 5 g in glass bottle
mp 204-206 °C (dec.) (lit.)
UNSPSC 12161600

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