Carbonyldihydridotris(triphenylphosphine)ruthenium(II)

ALDRICH/335002

Synonym: Dihydridocarbonyltris(triphenylphosphine)ruthenium

CAS Number: 25360-32-1
Empirical Formula (Hill Notation): C₅₅H₄₇OP₃Rh
Molecular Weight: 919.79
MDL Number: MFCD00015870
Linear Formula: [(C₆H₅)₃P]₃Ru(CO)H₂
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-335002-1G	1 g	$180.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

InChI	1S/3C18H15P.CO.Ru.2H/c31-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;;/h31-15H;;;;
InChI key	MLIYPCQSOXNTLJ-UHFFFAOYSA-N
mp	161-163 °C (lit.)
Quality Level	100
reaction suitability	core: ruthenium
	reagent type: catalyst reaction type: C-H Activation
SMILES string	[RuH2].[C-]#[O+].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9

Application:	• Catalyst for conversion of 1,4-alkynediols into pyrroles • Catalyst for oxidation of primary alcohols to methyl esters • Catalyst for rearrangement of oximes to amides • Catalyst for C-C coupling via directed C-H activation • Catalyst for enyne cyclization
Packaging:	1 g in glass bottle

Symbol	GHS07
Signal word	Warning
Hazard statements	H302 + H312 + H332
Precautionary statements	P261 - P264 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312
Hazard Codes	Xn
Risk Statements	20/21/22
Safety Statements	36
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

mp	161-163 °C (lit.)
UNSPSC	12352202

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