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[1,3-Bis(diphenylphosphino)propane]dichloronickel(II)

ALDRICH/335363

Synonym: (1,3-dppp)NiCl2; 1,3-Bis(diphenylphosphino)propane nickel(II) chloride; Ni(dppp)Cl2

CAS Number: 15629-92-2
Empirical Formula (Hill Notation): C27H26Cl2NiP2
Molecular Weight: 542.04
MDL Number: MFCD00015318
Linear Formula: [(C6H5)2P(CH2)3P(C6H5)2]NiCl2
Product Type: Chemical

Catalog Number PKG Qty. Price Quantity
45-335363-5G 5 g
$84.60
1/EA
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45-335363-25G 25 g
$157.00
1/EA
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This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 335363-25G

 

form powder
InChI 1S/C27H26P2.2ClH.Ni/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27;;;/h1-12,14-21H,13,22-23H2;2*1H;/q;;;+2/p-2
InChI key ZBQUMMFUJLOTQC-UHFFFAOYSA-L
mp 213 °C (dec.) (lit.)
reaction suitability core: nickel
  reaction type: Cross Couplings
  reagent type: catalyst
SMILES string Cl[Ni]Cl.C(CP(c1ccccc1)c2ccccc2)CP(c3ccccc3)c4ccccc4
Application: Catalyst for:
• Synthesis of block-copolythiophenes
• Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acids
• Solid state metathesis polycondensation
• Polymerization of poly(3-alkoxythiophene)s
• Diastereoselective Nozaki-Hiyama-Kishi coupling reactions of C1-C19 fragment of macrolide antibiotic aplyronine A
• Transfer condensation polymerization of conjugated polymers
Application: [1,3-Bis(diphenylphosphino)propane]dichloronickel(II) can be used as a precursor to synthesize metal-fullerene coordination complexes by reduction method.
Packaging: 5, 25 g in glass bottle
mp 213 °C (dec.) (lit.)
UNSPSC 12161600

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