[1,3-Bis(diphenylphosphino)propane]dichloronickel(II)
ALDRICH/335363
Synonym: (1,3-dppp)NiCl2; 1,3-
CAS Number: 15629-92-2
Empirical Formula (Hill Notation): C27H26Cl2NiP2
Molecular Weight: 542.04
MDL Number: MFCD00015318
Linear Formula: [(C6H5)2P(CH2)3P(C6H5)2]NiCl2
Product Type: Chemical
form | powder |
InChI | 1S/C27H26P2.2ClH.Ni/c1-5- |
InChI key | ZBQUMMFUJLOTQC-UHFFFAOYSA |
mp | 213 °C (dec.) (lit.) |
reaction suitability | core: nickel |
reaction type: Cross Couplings | |
reagent type: catalyst | |
SMILES string | Cl[Ni]Cl.C(CP(c1ccccc1)c2 |
Application: | Catalyst for: • Synthesis of block-copolythiophenes • Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acids • Solid state metathesis polycondensation • Polymerization of poly(3-alkoxythiophene)s • Diastereoselective Nozaki-Hiyama-Kishi coupling reactions of C1-C19 fragment of macrolide antibiotic aplyronine A • Transfer condensation polymerization of conjugated polymers |
Application: | [1,3-Bis(diphenylphosphin |
Packaging: | 5, 25 g in glass bottle |
Symbol | GHS07,GHS08 |
Signal word | Danger |
Hazard statements | H315 - H317 - H319 - H334 - H335 - H350 |
Precautionary statements | P201 - P280 - P302 + P352 - P305 + P351 + P338 - P308 + P313 |
Hazard Codes | T |
Risk Statements | 49-36/37/38-42/43 |
Safety Statements | 53-26-36/37/39-45 |
RIDADR | NONH for all modes of transport |
WGK Germany | WGK 3 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
mp | 213 °C (dec.) (lit.) |
UNSPSC | 12161600 |