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(1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-iridium(I) hexafluorophosphate

ALDRICH/337498 - 85%

Synonym: (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-Ir(I) PF6; Crabtree’s catalyst; Iridium(I) hexafluorophosphate (1,5-Cyclooctadiene)-(pyridine)-(tricyclohexylphosphine) complex; [Ir(cod)(PCy3)(py)]PF6

CAS Number: 64536-78-3
Empirical Formula (Hill Notation): C31H50F6IrNP2
Molecular Weight: 804.89
MDL Number: MFCD00075097
Linear Formula: C31H50F6IrNP2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-337498-50MG 50 mg
 $0.00
1/EA
CALL FOR PRICE		 Add To Favorites
45-337498-250MG 250 mg
 $176.00
1/EA		 Add To Favorites

 

assay 85%
InChI 1S/C18H33P.C8H12.C5H5N.F6P.Ir/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-4-6-8-7-5-3-1;1-2-4-6-5-3-1;1-7(2,3,4,5)6;/h16-18H,1-15H2;1-2,7-8H,3-6H2;1-5H;;/q;;;-1;+1/b;2-1-,8-7-;;;
InChI key UJXHUUQZACSUOG-KJWGIZLLSA-N
mp 175 °C (dec.) (lit.)
reaction suitability core: iridium
  reagent type: catalyst
SMILES string [Ir+].c1ccncc1.F[P-](F)(F)(F)(F)F.C2CC=CCCC=C2.C3CCC(CC3)P(C4CCCCC4)C5CCCCC5
Application: Catalyst for alkene hydrogenation, isomerization, and hydroboration; also for hydrogen isotope exchange reaction.
Application: Homogeneous hydrogenation catalyst hydroboration catalyst.
Packaging: 50, 250 mg in glass bottle
Purity 85%
mp 175 °C (dec.) (lit.)
UNSPSC 12161600

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