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Hydroquinine

ALDRICH/337714 - 98%

Synonym: (8a,9R)-10,11-Dihydro-6′-methoxycinchonan-9-ol; Dihydroquinine; NSC 41799

CAS Number: 522-66-7
Empirical Formula (Hill Notation): C20H26N2O2
Molecular Weight: 326.43
EC Number: 208-334-0
MDL Number: MFCD00151107
Linear Formula: C20H26N2O2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-337714-5G 5 g
 $229.00
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assay 98%
form powder
InChI 1S/C20H26N2O2/c1-3-13-12-22-9-7-14(13)10-19(22)20(23)16-6-8-21-18-5-4-15(24-2)11-17(16)18/h4-6,8,11,13-14,19-20,23H,3,7,9-10,12H2,1-2H3/t13-,14-,19-,20+/m0/s1
InChI key LJOQGZACKSYWCH-WZBLMQSHSA-N
mp 168-176 °C (lit.)
optical activity [α]25/D −148°, c = 1 in ethanol
SMILES string CC[C@H]1CN2CCC1C[C@@H]2[C@H](O)c3ccnc4ccc(OC)cc34
Application: Hydroquinine may be used in the preparation of its derivatives such as C9 epihydroquinine, 9-acetoxy-10,11-dihydroquinine and 10,11-dihydroquinine monohydrochloride. It may also be used as a catalyst for the methylhydrazine promoted asymmetric α-hydroxylation of β-keto esters in the presence of molecular oxygen as oxidant to form enantioenriched α-hydroxy β-dicarbonyl compounds.
General description: Hydroquinine is a cinchona alkaloid.
Packaging: 5 g in glass bottle
Purity 98%
mp 168-176 °C (lit.)
UNSPSC 12352005

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