Chlorodiisopropylphosphine

ALDRICH/337773 - 96%

Synonym: Diisopropylphosphine chloride

CAS Number: 40244-90-4
Empirical Formula (Hill Notation): C₆H₁₄ClP
Molecular Weight: 152.60
MDL Number: MFCD00015027
Linear Formula: [(CH₃)₂CH]₂PCl
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-337773-5G	5 g	$85.10 1/EA	Add To Favorites
45-337773-25G	25 g	$247.00 1/EA	Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	96%
bp	69 °C/33 mmHg (lit.)
density	0.959 g/mL at 25 °C (lit.)
form	liquid
functional group	phosphine
InChI	1S/C6H14ClP/c1-5(2)8(7)6(3)4/h5-6H,1-4H3
InChI key	JZPDBTOWHLZQFC-UHFFFAOYSA-N
reaction suitability	reagent type: ligand reaction type: Arylations
refractive index	n20/D 1.475 (lit.)
SMILES string	CC(C)P(Cl)C(C)C

Application:

Chlorodiisopropylphosphine can be used:
• To synthesize p-styryldiisopropylphosphine by reacting with 4-chlorostyrene via Grignard reaction.
• As a phosphination reagent in combination with [Cp2Zr(1-butene)(DMAP)] (Cp=cyclopentadienyl; DMAP= 4-(dimethylamino)pyridine)) for the zirconophosphination of alkynes to form zirconoalkenylphosphines.
• A luminescent mixed-donor platinum POCN pincer complex via cyclometalation process.

Packaging:

5, 25 g in glass bottle

Symbol	GHS02,GHS05
Signal word	Danger
Hazard statements	H225 - H314
Precautionary statements	P210 - P233 - P240 - P280 - P303 + P361 + P353 - P305 + P351 + P338
Hazard Codes	F,C
Risk Statements	11-34
Safety Statements	16-26-27-36/37/39-45
RIDADR	UN 2924 8(3) / PGII
WGK Germany	WGK 3
Flash Point(F)	39.2 °F - closed cup
Flash Point(C)	4 °C - closed cup

Purity	96%
bp	69 °C/33 mmHg (lit.)
Density	0.959 g/mL at 25 °C (lit.)
Refractive Index	n20/D 1.475 (lit.)
UNSPSC	12352001

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