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Pentamethylcyclopentadienylrhodium(III) chloride dimer

ALDRICH/338370 - 97%

Synonym: 1,3-Cyclopentadiene, 1,2,3,4,5-pentamethyl-, rhodium complex; Bis(dichloro(pentamethylcyclopentadienyl)rhodium); Bis(pentamethylcyclopentadienylrhodium dichloride); Dichloro(pentamethylcyclopentadienyl)rhodium(II) dimer; Tetrachlorobis(pentamethylcyclopentadienyl)dirhodium

CAS Number: 12354-85-7
Empirical Formula (Hill Notation): C20H30Cl4Rh2
Molecular Weight: 618.08
MDL Number: MFCD00061552
Linear Formula: [Rh(C5Me5)Cl2]2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-338370-250MG 250 mg
 $355.00
1/EA		 Add To Favorites
45-338370-1G 1 g
 $881.00
1/EA		 Add To Favorites
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 338370-1G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 338370-250MG

 

assay 97%
form solid
InChI 1S/2C10H15.4ClH.2Rh/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*1-5H3;4*1H;;/q;;;;;;2*+2/p-4
InChI key QNIVKTTWBMFSBR-UHFFFAOYSA-J
reaction suitability core: rhodium
  reaction type: C-H Activation
  reagent type: catalyst
reaction type: C-Mannosylation
SMILES string Cl[Rh]Cl.Cl[Rh]Cl.C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C
Application: Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis 

Catalyst for:
• Oxidative olefination reactions
• C-C bond cleavage of secondary alcohols
• Ortho C-H olefination of phenol derivatives
• Oxidative annulation of pyridines
• Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond
• Amidation reactions
• Reductive alkylation reactions
Application: Pentamethylcyclopentadienylrhodium(III) chloride dimer can be used as a catalyst for:
• Oxidative olefination reactions
• C-C bond cleavage of secondary alcohols
• Ortho C-H olefination of phenol derivatives
• Oxidative annulation of pyridines
• Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond
• Amidation reactions
• Reductive alkylation reactions
Packaging: 1 g in glass bottle
Packaging: 250 mg in glass bottle
Purity 97%
UNSPSC 12161600

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