Pentamethylcyclopentadienylrhodium(III) chloride dimer

ALDRICH/338370 - 97%

Synonym: 1,3-Cyclopentadiene, 1,2,3,4,5-pentamethyl-, rhodium complex; Bis(dichloro(pentamethylcyclopentadienyl)rhodium); Bis(pentamethylcyclopentadienylrhodium dichloride); Dichloro(pentamethylcyclopentadienyl)rhodium(II) dimer; Tetrachlorobis(pentamethylcyclopentadienyl)dirhodium

CAS Number: 12354-85-7
Empirical Formula (Hill Notation): C₂₀H₃₀Cl₄Rh₂
Molecular Weight: 618.08
MDL Number: MFCD00061552
Linear Formula: [Rh(C₅Me₅)Cl₂]₂
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-338370-250MG	250 mg	$378.00 1/EA	Add To Favorites
45-338370-1G	1 g	$938.00 1/EA	Add To Favorites

FT-NMR Spectra for 1,3-Cyclopentadiene, 1,2,3,4,5-pentamethyl-, rhodium complex.

This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 338370-1G

Properties
Descriptions
Safety Info.
Basic Data

assay	97%
form	solid
InChI	1S/2C10H15.4ClH.2Rh/c21-6-7(2)9(4)10(5)8(6)3;;;;;;/h21-5H3;41H;;/q;;;;;;2+2/p-4
InChI key	QNIVKTTWBMFSBR-UHFFFAOYSA-J
Quality Level	100
reaction suitability	core: rhodium
	reaction type: C-H Activation
	reagent type: catalyst reaction type: C-Mannosylation
SMILES string	Cl[Rh]Cl.Cl[Rh]Cl.C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C

Application:	Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis Catalyst for: • Oxidative olefination reactions • C-C bond cleavage of secondary alcohols • Ortho C-H olefination of phenol derivatives • Oxidative annulation of pyridines • Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp² C-H bond • Amidation reactions • Reductive alkylation reactions
Application:	Pentamethylcyclopentadienylrhodium(III) chloride dimer can be used as a catalyst for: • Oxidative olefination reactions • C-C bond cleavage of secondary alcohols • Ortho C-H olefination of phenol derivatives • Oxidative annulation of pyridines • Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp² C-H bond • Amidation reactions • Reductive alkylation reactions
Packaging:	1 g in glass bottle
Packaging:	250 mg in glass bottle

Symbol	GHS07
Signal word	Warning
Hazard statements	H302 + H312 + H332 - H315
Precautionary statements	P261 - P264 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312
Hazard Codes	Xn
Risk Statements	20/21/22-36/37/38
Safety Statements	26-36
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Purity	97%
UNSPSC	12161600

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