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Tetrakis(acetonitrile)palladium(II) tetrafluoroborate

ALDRICH/339768

Synonym: NSC 307191; Palladium(II) tetrafluoroborate tetraacetonitrile complex

CAS Number: 21797-13-7
Empirical Formula (Hill Notation): C8H12B2F8N4Pd
Molecular Weight: 444.24
MDL Number: MFCD00043297
Linear Formula: Pd(CH3CN)4(BF4)2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-339768-250MG 250 mg
 $71.30
1/EA		 Add To Favorites
45-339768-1G 1 g
 $255.00
1/EA		 Add To Favorites
Pd(CH3CN)4(BF4)2
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 339768-250MG

 

form solid
InChI 1S/4C2H3N.2BF4.Pd/c4*1-2-3;2*2-1(3,4)5;/h4*1H3;;;/q;;;;2*-1;+2
InChI key YWMRPVUMBTVUEX-UHFFFAOYSA-N
mp 230 °C (dec.) (lit.)
reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Cross Couplings
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: catalyst
core: palladium
  reagent type: ligand
SMILES string [Pd++].CC#N.CC#N.CC#N.CC#N.F[B-](F)(F)F.F[B-](F)(F)F
Application: Application Guide for Palladium Catalyzed Cross-Coupling Reactions 

Reactant involved in:
• Reactions where it plays a role as the metal source due to weakly coordinated acetonitrile ligands

Precursor for:
• Synthesis of dendritic SCS-pincer palladium complexes
• Palladium complexes of click ligands
• Dipalladium catalysts for use in Heck cross-coupling, Suzuki cross-coupling, and aldehyde olefination
General description: Tetrakis(acetonitrile)palladium(II) tetrafluoroborate is a stronger Lewis acid. It participates in the preparation of 2:1 complex [Pd(1,2-bis(2′-pyridylethynyl)benzene)2](BF4]2, by Sonogashira cross-coupling reaction.
Packaging: 1 g in glass bottle
Packaging: 250 mg in glass bottle
Symbol GHS07  GHS07
Signal word Warning
Hazard statements H332
Hazard Codes Xn
Risk Statements 20
Safety Statements 22-36/37/39-38
RIDADR NONH for all modes of transport
mp 230 °C (dec.) (lit.)
UNSPSC 12161600

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