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Dibromodifluoromethane

ALDRICH/34125 - ≥95.0% (GC)

Synonym: Carbon dibromide difluoride; Difluorodibromomethane

CAS Number: 75-61-6
Empirical Formula (Hill Notation): CBr2F2
Molecular Weight: 209.82
EC Number: 200-885-5
MDL Number: MFCD00000367
Linear Formula: CBr2F2
Product Type: Chemical

Catalog Number PKG Qty. Price Quantity
45-34125-25ML 25 mL
$421.00
1/EA
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assay ≥95.0% (GC)
bp 22-23 °C (lit.)
density 2.297 g/mL at 25 °C (lit.)
form liquid
InChI 1S/CBr2F2/c2-1(3,4)5
InChI key AZSZCFSOHXEJQE-UHFFFAOYSA-N
mp −142-−141 °C (lit.)
refractive index n20/D 1.398
  n20/D 1.398 (lit.)
SMILES string FC(F)(Br)Br
storage temp. 2-8°C
vapor density 7.24 (vs air)
vapor pressure 12.79 psi ( 20 °C)
Application:
  • Synthesis of 3‑Fluoropyrazoles via Radical-Polar Crossover Photoinduced Cyclization: This study highlights the use of dibromodifluoromethane (CF2Br2) for the synthesis of valuable difluorinated and monofluorinated compounds through a novel photoinduced cyclization process (MA Reed, ND Patil, Synfacts, 2023 ).
General description: The photolysis products of dibromodifluoromethane were characterized by matrix isolation infrared and UV/Visible spectroscopy. Free radical addition of dibromodifluoromethane with fluoroolefins has been reported. Dibromodifluoromethane reacts with hydrocarbon olefins to yield 1,3-dibromo-1,1-difluoroalkene. Sulfinatodehalogenation reagent promoted addition reaction of difluorodibromomethane with alkenes, alkynes and cyclic enol ethers has been described.
Other Notes: Reagent for the Wittig olefination of carbonyl compounds to difluoromethylene and fluoromethylene derivatives; Precursor of difluorocarbene
Packaging: 25 mL in glass bottle
Purity ≥95.0% (GC)
bp 22-23 °C (lit.)
mp −142-−141 °C (lit.)
Density 2.297 g/mL at 25 °C (lit.)
Refractive Index n20/D 1.398 (lit.); n20/D 1.398
Storage Temp. 2-8°C
UNSPSC 12352100

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