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Bis(diisopropylamino)chlorophosphine

ALDRICH/341347 - ≥95.0%

Synonym: Chlorobis(N,N-diisopropyl)phosphoramidite; Chlorobis(N,N-diisopropylamino)phosphine; Tetraisopropylphosphorodiamidous chloride

CAS Number: 56183-63-2
Empirical Formula (Hill Notation): C12H28ClN2P
Molecular Weight: 266.79
MDL Number: MFCD00061482
Linear Formula: [[(CH3)2CH]2N]2PCl
Product Type: Chemical

Catalog Number PKG Qty. Price Quantity
45-341347-5G 5 g
$94.30
1/EA
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This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 341347-5G

 

assay ≥95.0%
functional group phosphine
InChI 1S/C12H28ClN2P/c1-9(2)14(10(3)4)16(13)15(11(5)6)12(7)8/h9-12H,1-8H3
InChI key FEHUTHGOLLQBNW-UHFFFAOYSA-N
mp 100-104 °C (lit.)
Quality Level 100 
reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
SMILES string CC(C)N(C(C)C)P(Cl)N(C(C)C)C(C)C
Application: Bis(diisopropylamino)chlorophosphine has been used in the synthesis of tert-butyl tetraisopropylphosphorodiamidite ligand for palladium-catalyzed Buchwald–Hartwig amination reaction.

It is also can be used to synthesize:
• acyclic N-phosphonio imine catalyst for selective epoxidations
• boryl-substituted methylenephosphonium derivatives

Other Notes: Contains varying amounts of diisopropylamine hydrochloride
Packaging: 5 g in glass bottle
Purity ≥95.0%
mp 100-104 °C (lit.)
UNSPSC 12352001

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