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Bromopentacarbonylmanganese(I)

ALDRICH/341622 - 98%

Synonym: Bromopentacarbonylmanganese(I); Manganese pentacarbonyl bromide

CAS Number: 14516-54-2
Empirical Formula (Hill Notation): C5BrMnO5
Molecular Weight: 274.89
EC Number: 238-522-8
MDL Number: MFCD00049806
Linear Formula: BrMn(CO)5
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-341622-5G 5 g
 $322.00
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This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 341622-5G

 

assay 98%
form powder or crystals
InChI 1S/5CO.BrH.Mn/c5*1-2;;/h;;;;;1H;/q;;;;;;+1/p-1
InChI key OESORJHGSXJTKX-UHFFFAOYSA-M
Quality Level 100 
reaction suitability core: manganese
  reagent type: catalyst
SMILES string [Mn]Br.[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
storage temp. 2-8°C
Application: Bromopentacarbonylmanganese(I) can be used as:
• A precursor to synthesize manganese complex, [Mn(CO)5H], which was then used as a catalyst in the reduction of levulinic acid (LA) to methyltetrahydrofuran (MTHF) and the reductive amination of LA to N-substituted pyrrolidines.
• A precursor to prepare Mn(I) complexes bearing bifunctional ligands, which are used as catalysts for the transfer-hydrogenation of various ketones and imines using 2-propanol as the hydrogen donor.
• A catalyst in the selective C2-H activation reactions.
General description: Bromopentacarbonylmanganese(I)is an organomanganese compound with a central manganese atom at its core,enclosed by five carbon monoxide ligands and one bromine atom. It is commonlyused as a reagent in organic synthesis, particularly in carbonylationreactions. It is also used as a precursor for the preparation of various manganesecomplexes.
Packaging: 5 g in glass bottle
Purity 98%
Storage Temp. 2-8°C
UNSPSC 12352103

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