Bromopentacarbonylmanganese(I)
ALDRICH/341622 - 98%
Synonym: Bromopentacarbonylmanganese(I); Manganese pentacarbonyl bromide
CAS Number: 14516-54-2
Empirical Formula (Hill Notation): C5BrMnO5
Molecular Weight: 274.89
EC Number: 238-522-8
MDL Number: MFCD00049806
Linear Formula: BrMn(CO)5
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 341622-5G
| assay | 98% |
| form | powder or crystals |
| InChI | 1S/5CO.BrH.Mn/c5*1-2;;/h; |
| InChI key | OESORJHGSXJTKX-UHFFFAOYSA |
| reaction suitability | core: manganese |
| reagent type: catalyst | |
| SMILES string | [Mn]Br.[C-]#[O+].[C-]#[O+ |
| storage temp. | 2-8°C |
| Application: | Bromopentacarbonylmangane • A precursor to synthesize manganese complex, [Mn(CO)5H], which was then used as a catalyst in the reduction of levulinic acid (LA) to methyltetrahydrofuran (MTHF) and the reductive amination of LA to N-substituted pyrrolidines. • A precursor to prepare Mn(I) complexes bearing bifunctional ligands, which are used as catalysts for the transfer-hydrogenation of various ketones and imines using 2-propanol as the hydrogen donor. • A catalyst in the selective C2-H activation reactions. |
| Packaging: | 5 g in glass bottle |
| Symbol |  GHS07 |
| Signal word | Warning |
| Hazard statements | H302 + H312 + H332 |
| Precautionary statements | P280 - P301 + P312 + P330 - P302 + P352 + P312 - P304 + P340 + P312 |
| Hazard Codes | Xn |
| Risk Statements | 20/21/22 |
| Safety Statements | 36 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | 98% |
| Storage Temp. | 2-8°C |
| UNSPSC | 12352103 |