Dichloro(p-cymene)ruthenium(II) dimer

ALDRICH/343706

Synonym: (p-Cymene)ruthenium(II) chloride dimer; Benzene, 1-methyl-4-(1-methylethyl)-, ruthenium complex

CAS Number: 52462-29-0
Empirical Formula (Hill Notation): C₂₀H₂₈Cl₄Ru₂
Molecular Weight: 612.39
MDL Number: MFCD00064793
Linear Formula: [Ru(p-cymene)Cl₂]₂
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-343706-1G	1 g	$76.40 1/EA	Add To Favorites
45-343706-5G	5 g	$247.00 1/EA	Add To Favorites

This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 343706-1G

12 Principles of Green Chemistry: Principle 9—Catalytic reagents (as selective as possible) are superior to stoichiometric reagents.

Properties
Descriptions
Safety Info.
Basic Data

greener alternative category	, Aligned
greener alternative product characteristics	Catalysis Learn more about the Principles of Green Chemistry .
InChI	1S/2C10H14.4ClH.2Ru/c21-8(2)10-6-4-9(3)5-7-10;;;;;;/h24-8H,1-3H3;41H;;/q;;;;;;2+2/p-4
InChI key	LAXRNWSASWOFOT-UHFFFAOYSA-J
mp	247.0-250.0 °C (dec.) (lit.)
reaction suitability	core: ruthenium
	reagent type: catalyst reaction type: C-H Activation
SMILES string	Cl[Ru]Cl.Cl[Ru]Cl.CC(C)c1ccc(C)cc1.CC(C)c2ccc(C)cc2
sustainability	Greener Alternative Product

Application:	Hydrosilylation Catalysts
Application:	Catalyst for greener amine synthesis by reduction of imines with PMHS or hydrogen-borrowing. A Practical and Benign Synthesis of Primary Amines through Ruthenium-Catalyzed Reduction of Nitriles Ruthenium-Catalyzed N-Alkylation of Amines and Sulfonamides Using Borrowing Hydrogen Methodology
Application:	Cyclometalated ruthenium complexes with arylimines and nitrogen-containing heterocycles via C-H bond activation
General description:	We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information. Dichloro(p-cymene)ruthenium(II) dimer is a saturated 18-electron complex used as a starting material for the synthesis of organometallic complexes.
Packaging:	1, 5 g in glass bottle

Symbol	GHS07
Signal word	Warning
Hazard statements	H319
Precautionary statements	P264 - P280 - P305 + P351 + P338 - P337 + P313
Hazard Codes	Xn
Risk Statements	22-36-52/53
Safety Statements	26-61
RIDADR	NONH for all modes of transport
WGK Germany	WGK 2
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

mp	247.0-250.0 °C (dec.) (lit.)
UNSPSC	12161600

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