(1S)-(+)-(10-Camphorsulfonyl)oxaziridine
ALDRICH/345350
Synonym: (1S)
CAS Number: 104322-63-6
Empirical Formula (Hill Notation): C10H15NO3S
Molecular Weight: 229.30
MDL Number: MFCD21332910
Linear Formula: C10H15NO3S
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 345350-1G
| form | solid |
| impurities | <1% toluene |
| InChI | 1S/C10H15NO3S/c1-8(2)7-3- |
| InChI key | GBBJBUGPGFNISJ-YDQXZVTASA |
| mp | 172-174 °C (lit.) |
| optical activity | [α]28/D +45°, c = 2 in chloroform |
| SMILES string | CC1(C)[C@@H]2CC[C@]13CS(= |
| storage temp. | 2-8°C |
| Application: | (1S)-(+)-(10-Camphorsulfonyl • To convert prochiral ketone enolates into optically active α-hydroxy ketones via enantioselective asymmetric oxidation. • In the synthesis of thymidine oligonucleotides connected through pyrophosphates. • In the asymmetric synthesis of proton pump inhibitors like (R)-Rabeprazole sodium and (R)-Lansoprazole sodium from the corresponding DBU salt of prochiral sulfide. • In the preparation of phosphonoacetate and thiophosphonoacetate oligodeoxynucleotides by oxidizing the corresponding phosphinoacetate. |
| Packaging: | 1 g in glass bottle |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| mp | 172-174 °C (lit.) |
| Storage Temp. | 2-8°C |
| UNSPSC | 12352005 |