(Triethylsilyl)acetylene
ALDRICH/346977 - 97%
Synonym: Ethynyltriethylsilane
CAS Number: 1777-03-3
Empirical Formula (Hill Notation): C8H16Si
Molecular Weight: 140.30
MDL Number: MFCD00075373
Linear Formula: (C2H5)3SiC≡CH
Product Type: Chemical
assay | 97% |
density | 0.783 g/mL at 25 °C (lit.) |
form | liquid |
InChI | 1S/C8H16Si/c1-5-9(6-2,7-3 |
InChI key | FWSPXZXVNVQHIF-UHFFFAOYSA |
refractive index | n |
SMILES string | CC[Si](CC)(CC)C#C |
Application: | (Triethylsilyl)acetylene may be used in the synthesis of triethylsilylethynyl anthradithiophenes, such as : • 2,8-dimethyl-5,11-bis(t • 2,8-diethyl-5,11-bis(tr • 2,8-dipropyl-5,11-bis(t |
General description: | (Triethylsilyl)acetylene, a bulky trialkylsilyl-protected alkyne, undergoes Cadiot-Chodkiewicz cross-coupling reaction with various bromoalkynes to yield synthetically useful unsymmetrical diynes. Rhodium-catalyzed dimerization of (triethylsilyl)acetylene has been reported. |
Packaging: | 5 g in glass bottle |
Symbol | GHS02 |
Signal word | Danger |
Hazard statements | H225 |
Precautionary statements | P210 - P370 + P378 - P403 + P235 |
Hazard Codes | F,Xi |
Risk Statements | 11-36/37/38 |
Safety Statements | 16-26-36/37/39 |
RIDADR | UN 1993BF 3 / PGII |
WGK Germany | WGK 3 |
Flash Point(F) | 62.6 °F - closed cup |
Flash Point(C) | 17 °C - closed cup |
Purity | 97% |
Density | 0.783 g/mL at 25 °C (lit.) |
Refractive Index | n |
UNSPSC | 12352100 |