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Boron trichloride solution

ALDRICH/348325 - 1.0 M in heptane

Synonym: Boron chloride; Trichloroborane

CAS Number: 10294-34-5
Empirical Formula (Hill Notation): BCl3
Molecular Weight: 117.17
MDL Number: MFCD00011313
Linear Formula: BCl3
Product Type: Chemical

Catalog Number PKG Qty. Price Quantity
45-348325-4X25ML 25 mL
$68.70
4/EA
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45-348325-100ML 100 mL
$72.20
1/EA
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45-348325-800ML 800 mL
$363.00
1/EA
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25 mL Sure/Sealâ„¢ Packaging

 

concentration 1.0 M in heptane
density 0.74 g/mL at 25 °C
form liquid
InChI 1S/BCl3/c2-1(3)4
InChI key FAQYAMRNWDIXMY-UHFFFAOYSA-N
reaction suitability core: boron
  reagent type: catalyst
  reagent type: Lewis acid
SMILES string ClB(Cl)Cl
storage temp. 2-8°C
Application: • Boron trichloride, a Lewis acid, is a general reagent for the cleavage of a wide range of ether and acetal protecting groups.
• It is a useful reagent to directly convert aromatic aldehydes to the corresponding gem-dichlorides.
• It can also be used in the transmetallation reaction with less nucleophilic reagents such as tin and zirconium organometallic compounds to synthesize a variety of organoboranes.

Application: For preparing methyl esters of fatty acids and for transesterification of triglycerides.
Legal Information: Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
Packaging: 4×25, 100, 800 mL in Sure/Seal™
Packaging: The 25 mL Sure/Seal bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
Symbol GHS02GHS05GHS06GHS08GHS09  GHS02,GHS05,GHS06,GHS08,GHS09
Signal word Danger
Hazard statements H225 - H300 - H304 - H314 - H331 - H336 - H360FD - H410
Precautionary statements P210 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
Hazard Codes F,T+,N
Risk Statements 11-14-26/28-34-50/53-65
Safety Statements 26-28-36/37/39-45-61-62
RIDADR UN2924 - class 3 - PG 2 - EHS - acidic - Flammable liquids, corr
WGK Germany WGK 3
Flash Point(F) 35.6 °F - closed cup
Flash Point(C) 2 °C - closed cup
Supplemental Hazard Statements EUH014
Density 0.74 g/mL at 25 °C
Storage Temp. 2-8°C
UNSPSC 12352106

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