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(1R)-(−)-(10-Camphorsulfonyl)oxaziridine

ALDRICH/349003

Synonym: (1R)-(−)-(Camphorylsulfonyl)oxaziridine; (1R)-(−)-2,N-Epoxy-exo-10,2-bornanesultam

CAS Number: 104372-31-8
Empirical Formula (Hill Notation): C10H15NO3S
Molecular Weight: 229.30
MDL Number: MFCD00075428
Linear Formula: C10H15NO3S
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-349003-1G 1 g
 $200.00
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form powder
InChI 1S/C10H15NO3S/c1-8(2)7-3-4-9(8)6-15(12,13)11-10(9,5-7)14-11/h7H,3-6H2,1-2H3/t7-,9-,10?,11?/m1/s1
InChI key GBBJBUGPGFNISJ-JRNSMZEGSA-N
optical activity [α]20/D −44°, c = 2.2 in chloroform
Quality Level 100 
SMILES string [H][C@@]12CC[C@@]3(CS(=O)(=O)N4OC34C1)C2(C)C
storage temp. 2-8°C
Application: (1R)-(-)-(10-Camphorsulfonyl)oxaziridine may be used as an oxidant to prepare (S)-(-)-vasicinone via asymmetric oxidation of deoxyvasicinone.
Application: Reactant involved in:
• Asymmetric synthesis of proton pump inhibitors
• Asymmetric synthesis of polyhydroxylated pyrrolidines
• Diastereoselective hydroxylation of chlorophylls a and b enolate anions

Used in impregnated silica nanoparticles for removal of sulfur mustard from wastewater

Used to modify blebbistatin for investigations of myosin inhibitor design
Packaging: 1 g in glass bottle
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Storage Temp. 2-8°C
UNSPSC 12352005

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