(+)-Chloromethyl menthyl ether

ALDRICH/349925 - 97%

CAS Number: 103128-76-3
Empirical Formula (Hill Notation): C₁₁H₂₁ClO
Molecular Weight: 204.74
MDL Number: MFCD09039273
Linear Formula: C₁₁H₂₁ClO
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-349925-5G	5 g	$175.00 1/EA	Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	97%
bp	72 °C/0.4 mmHg (lit.)
density	0.994 g/mL at 25 °C (lit.)
form	liquid
InChI	1S/C11H21ClO/c1-8(2)10-5-4-9(3)6-11(10)13-7-12/h8-11H,4-7H2,1-3H3/t9-,10+,11-/m0/s1
InChI key	XOPLTFUYFXWFGB-AXFHLTTASA-N
optical activity	[α]24/D +181.0°, c = 2 in methylene chloride
optical purity	ee: 98% (GLC)
refractive index	n20/D 1.467 (lit.)
SMILES string	CC(C)[C@H]1CC[C@H](C)C[C@@H]1OCCl
storage temp.	−20°C

Application:

(+)-Chloromethyl menthyl ether can be used:
• As a starting material for the synthesis of 1-methyl-3-(+)-methylmenthoxide imidazolium chloride, a key intermediate for the preparation of Ag(I) N-heterocyclic carbene, applicable as a catalyst in the diboration of alkenes.
• As a substrate in the synthesis of commercially important O-substituted α-methoxymethylketones.
• To determine enantiomeric excess (ee) of an iron chiral auxiliary named [Fe(CO)(η;⁵- C₂H₅)(PPh₃)COCH₃].

Packaging:

5 g in glass bottle

Symbol	GHS07
Signal word	Warning
Hazard statements	H315 - H319 - H335
Precautionary statements	P302 + P352 - P305 + P351 + P338
Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-36
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	224.6 °F - closed cup
Flash Point(C)	107 °C - closed cup

Purity	97%
bp	72 °C/0.4 mmHg (lit.)
Density	0.994 g/mL at 25 °C (lit.)
Refractive Index	n20/D 1.467 (lit.)
Storage Temp.	−20°C
UNSPSC	12352101

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