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(+)-Chloromethyl menthyl ether

ALDRICH/349925 - 97%

CAS Number: 103128-76-3
Empirical Formula (Hill Notation): C11H21ClO
Molecular Weight: 204.74
MDL Number: MFCD09039273
Linear Formula: C11H21ClO
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-349925-5G 5 g
 $187.00
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assay 97%
bp 72 °C/0.4 mmHg (lit.)
density 0.994 g/mL at 25 °C (lit.)
form liquid
functional group chloro
  ether
InChI 1S/C11H21ClO/c1-8(2)10-5-4-9(3)6-11(10)13-7-12/h8-11H,4-7H2,1-3H3/t9-,10+,11-/m0/s1
InChI key XOPLTFUYFXWFGB-AXFHLTTASA-N
optical activity [α]24/D +181.0°, c = 2 in methylene chloride
optical purity ee: 98% (GLC)
Quality Level 100 
refractive index n20/D 1.467 (lit.)
SMILES string CC(C)[C@H]1CC[C@H](C)C[C@@H]1OCCl
storage temp. −20°C
Application: (+)-Chloromethyl menthyl ether can be used:
• As a starting material for the synthesis of 1-methyl-3-(+)-methylmenthoxide imidazolium chloride, a key intermediate for the preparation of Ag(I) N-heterocyclic carbene, applicable as a catalyst in the diboration of alkenes.
• As a substrate in the synthesis of commercially important O-substituted α-methoxymethylketones.
• To determine enantiomeric excess (ee) of an iron chiral auxiliary named [Fe(CO)(η;5- C2H5)(PPh3)COCH3].
Packaging: 5 g in glass bottle
Purity 97%
bp 72 °C/0.4 mmHg (lit.)
Density 0.994 g/mL at 25 °C (lit.)
Refractive Index n20/D 1.467 (lit.)
Storage Temp. −20°C
UNSPSC 12352101

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