Zirconium(IV) chloride
ALDRICH/357405 - ≥99.9% trace metals basis
Synonym: Tetrachlorozirconium; Zirconium tetrachloride
CAS Number: 10026-11-6
Empirical Formula (Hill Notation): Cl4Zr
Molecular Weight: 233.04
EC Number: 233-058-2
MDL Number: MFCD00011306
Linear Formula: ZrCl4
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 357405-100G.
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 357405-10G
| application(s) | battery manufacturing |
| assay | ≥99.9% trace metals basis |
| density | 2.8 g/mL at 25 °C (lit.) |
| form | powder |
| impurities | ≤1000.0 ppm Trace Metal Analysis |
| InChI | 1S/4ClH.Zr/h4*1H;/q;;;;+4 |
| InChI key | DUNKXUFBGCUVQW-UHFFFAOYSA |
| reaction suitability | reagent type: catalyst core: zirconium |
| SMILES string | Cl[Zr](Cl)(Cl)Cl |
| transition temp | sublimation point 331 °C |
| vapor pressure | 1 mmHg ( 190 °C) |
| Application: | Zirconium (IV) chloride acts as an efficient Lewis acid catalyst for various reactions; such as: • electrophilic addition reaction of indole with aldehydes/ketones to form bis(indolyl)methanes. electrophilic amination of activated arenes, • transthioacetylization of acetals, • deoxygenation of heterocyclic-N-oxides, • reduction of nitro compounds, • conversion of carbonyl compounds to 1,3-oxathiolanes, • Biginelli reaction for the synthesis of 3,4-dihydropyrimidin-2(1H • direct amide coupling of non activated carboxylic acids and amines, • synthesis of quinoxalines and pyrido[2,3-b]pyrazines, • deprotection of t-butyldimethylsilyl (TBDMS) ethers. Activates pyrrolidines for improved conversion, via a modified Bouveault reaction, to the corresponding α,α-dimethylamines. |
| Packaging: | 10, 100 g in glass bottle |
| Symbol |  GHS05 |
| Signal word | Danger |
| Hazard statements | H290 - H314 |
| Precautionary statements | P280 - P305 + P351 + P338 - P310 |
| Hazard Codes | C |
| Risk Statements | 14-35 |
| Safety Statements | 26-36/37/39-45 |
| RIDADR | UN 2503 8 / PGIII |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Supplemental Hazard Statements | EUH014 - EUH071 |
| Purity | ≥99.9% trace metals basis |
| Density | 2.8 g/mL at 25 °C (lit.) |
| UNSPSC | 12352302 |