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Pentamethylcyclopentadienyliridium(III) chloride,dimer

ALDRICH/357537 - 96%

Synonym: di-μ-chlorodichlorobis[(1,2,3,4,5-η)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-iridium

CAS Number: 12354-84-6
Empirical Formula (Hill Notation): C20H30Cl4Ir2
Molecular Weight: 796.70
MDL Number: MFCD00075435
Linear Formula: C20H30Cl4Ir2
Product Type: Chemical

Catalog Number PKG Qty. Price Quantity
45-357537-100MG 100 mg
$87.90
1/EA
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45-357537-500MG 500 mg
$236.00
1/EA
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This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 357537-100MG
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 357537-500MG
12 Principles of Green Chemistry: Principle 9—Catalytic reagents (as selective as possible) are superior to stoichiometric reagents.

 

assay 96%
form solid
greener alternative category Aligned ,  
greener alternative product characteristics Catalysis
Learn more about the Principles of Green Chemistry .
InChI 1S/2C10H15.4ClH.2Ir/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*1-5H3;4*1H;;/q;;;;;;2*+2/p-4
InChI key JDOHSXHCQARCAW-UHFFFAOYSA-J
reaction suitability core: iridium
  reagent type: catalyst
SMILES string Cl[Ir]Cl.Cl[Ir]Cl.C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C
sustainability Greener Alternative Product
Application: Catalyst for greener amine synthesis from amines and alcohols by hydrogen-borrowing. Precursor to cooperative metal-Bronsted acid catalyst for greener reductive amination using hydrogen gas.

Metal-Brønsted Acid Cooperative Catalysis for Asymmetric Reductive Amination 

Development of GSK's reagent guides – embedding sustainability into reagent selection 
General description: Pentamethylcyclopentadienyliridium(III) chloride, dimer is utilized as a catalyst in cross-coupling and dimerization reactions.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here  for more information.
Packaging: 100, 500 mg in glass bottle
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity 96%
UNSPSC 12161600

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