Dimethyl trimethylsilyl phosphite
ALDRICH/358819 - 95%
Synonym: Trimethylsilyl dimethyl phosphite
CAS Number: 36198-87-5
Empirical Formula (Hill Notation): C5H15O3PSi
Molecular Weight: 182.23
EC Number: 252-908-3
MDL Number: MFCD00075439
Linear Formula: (CH3)3SiOP(OCH3)2
Product Type: Chemical
| assay | 95% |
| bp | 36-37 °C/11 mmHg (lit.) |
| density | 0.954 g/mL at 25 °C (lit.) |
| form | liquid |
| InChI | 1S/C5H15O3PSi/c1-6-9(7-2) |
| InChI key | HWMXPTIFAGBDIK-UHFFFAOYSA |
| Quality Level | 200 ![]() |
| refractive index | n |
| SMILES string | COP(OC)O[Si](C)(C)C |
| storage temp. | 2-8°C |
| Application: | Dimethyl trimethylsilyl phosphite may be used in the preparation of: • protected phosphoamino acid, Fmoc-Abu(PO3Me2)-OH, used in Fmoc/solid-phase peptide synthesis • phosphoenolpyruvate (PEP) via trimethylsilylation, bromination and Perkow reaction • sialyl phosphonate • sulfonamide phosphonates |
| Packaging: | 10 mL in glass bottle |
| Symbol | ![]() GHS02,GHS05 |
| Signal word | Danger |
| Hazard statements | H226 - H314 |
| Precautionary statements | P280 - P305 + P351 + P338 - P310 |
| Hazard Codes | C |
| Risk Statements | 10-34 |
| Safety Statements | 26-36/37/39-45 |
| RIDADR | UN 2920 3(8) / PGII |
| WGK Germany | WGK 3 |
| Flash Point(F) | 89.6 °F - closed cup |
| Flash Point(C) | 32 °C - closed cup |
| Purity | 95% |
| bp | 36-37 °C/11 mmHg (lit.) |
| Density | 0.954 g/mL at 25 °C (lit.) |
| Refractive Index | n |
| Storage Temp. | 2-8°C |
| UNSPSC | 12352100 |



