Cerium(IV) sulfate
ALDRICH/359009
Synonym: Ceric sulfate; Cerium disulfate
CAS Number: 13590-82-4
Empirical Formula (Hill Notation): CeO8S2
Molecular Weight: 332.24
EC Number: 237-029-5
MDL Number: MFCD00148852
Linear Formula: Ce(SO4)2
Product Type: Chemical
density | 3.01 g/mL at 25 °C (lit.) |
form | powder |
InChI | 1S/Ce.2H2O4S/c;2*1-5(2,3) |
InChI key | VZDYWEUILIUIDF-UHFFFAOYSA |
Quality Level | 100 |
reaction suitability | core: cerium |
reagent type: catalyst | |
SMILES string | [Ce+4].[O-]S([O-])(=O)=O. |
Application: | Cerium(IV) sulfate can be used to catalyze: • Selective oxidation of secondary alcohols to the corresponding ketones using sodium bromate as the oxidant. • Direct sulfonation of methane with sulfur trioxide to methanesulfonic acid in sulfuric acid. • Synthesis of 14-aryl- or 14-alkyl-14H-dibenzo[aj]xanthenes from the condensation of 2-naphthol and aldehydes under solvent-free and microwave conditions. |
Application: | Reactant for: • Preparation of spherical-like nanoparticles CeO2 nanoparticles for NO reductions reactions • Oxidizing agent |
Other Notes: | may contain excess sulfate |
Packaging: | 25, 100 g in glass bottle |
Symbol | GHS05,GHS09 |
Signal word | Danger |
Hazard statements | H314 - H410 |
Precautionary statements | P260 - P273 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P305 + P351 + P338 |
Hazard Codes | Xi |
Risk Statements | 36/37/38 |
Safety Statements | 26-36 |
RIDADR | NONH for all modes of transport |
WGK Germany | WGK 3 |
Density | 3.01 g/mL at 25 °C (lit.) |
UNSPSC | 12161600 |