Sodium tert-butoxide
ALDRICH/359270 - 97%
Synonym: Sodium 2-
CAS Number: 865-48-5
Empirical Formula (Hill Notation): C4H9NaO
Molecular Weight: 96.10
EC Number: 212-741-9
MDL Number: MFCD00040575
Linear Formula: NaOC(CH3)3
Product Type: Chemical
assay | 97% |
InChI | 1S/C4H9O.Na/c1-4(2,3)5;/h |
InChI key | MFRIHAYPQRLWNB-UHFFFAOYSA |
SMILES string | [Na+].CC(C)(C)[O-] |
Application: | Sodium tert-butoxide may be used as a safe and effective alternative to sodium hydride for the coupling of hydroxyethyl adenine with diethyl p-toluenesulfonyloxymethan It can also be used: • To facilitate the coupling of aryl halides with benzene derivatives in the presence of 10-phenanthroline derivative. • To activate first-row transition-metal pre-catalysts. • As a base for the amination of aryl chlorides in the presence of a novel palladacyclic precatalyst. |
Packaging: | 1.5 kg in glass bottle |
Packaging: | 2.5 kg in poly bottle |
Packaging: | 5, 25, 100, 500 g in poly bottle |
Symbol | GHS02,GHS05 |
Signal word | Danger |
Hazard statements | H228 - H251 - H314 |
Precautionary statements | P210 - P235 - P260 - P280 - P303 + P361 + P353 - P305 + P351 + P338 |
Hazard Codes | F,C |
Risk Statements | 11-14-34-37 |
Safety Statements | 7/8-26-36/37/39-43-45 |
RIDADR | UN 3206 8(4.2) / PGII |
WGK Germany | WGK 1 |
Flash Point(F) | 57.2 °F |
Flash Point(C) | 14 °C |
Supplemental Hazard Statements | EUH014 |
Purity | 97% |
UNSPSC | 12352107 |