Hydroquinidine

ALDRICH/359343 - 95%

Synonym: (9S)-10,11-Dihydro-6′-methoxycinchonan-9-ol; Dihydroquinidine

CAS Number: 1435-55-8
Empirical Formula (Hill Notation): C₂₀H₂₆N₂O₂
Molecular Weight: 326.43
EC Number: 215-862-5
MDL Number: MFCD00135599
Linear Formula: C₂₀H₂₆N₂O₂
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-359343-5G	5 g	$59.40 1/EA	Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	95%
functional group	hydroxyl
InChI	1S/C20H26N2O2/c1-3-13-12-22-9-7-14(13)10-19(22)20(23)16-6-8-21-18-5-4-15(24-2)11-17(16)18/h4-6,8,11,13-14,19-20,23H,3,7,9-10,12H2,1-2H3/t13-,14-,19+,20-/m0/s1
InChI key	LJOQGZACKSYWCH-LHHVKLHASA-N
mp	169-170 °C (lit.)
optical activity	[α]25/D +226°, c = 2 in ethanol
Quality Level	100
SMILES string	CC[C@H]1CN2CCC1CC2[C@@H](O)c3ccnc4ccc(OC)cc34

Application:	Hydroquinidine can be used as a chiral catalyst to prepare: • Enantioselective axially chiral phosphamides by N-allylic alkylation reaction between Morita-Baylis-Hillamn (MBH) carbonate and phosphamides. • Enantioselective α-amino phosphonates by hydrophosphonylation of N-aryl ketimines. • Enantioselective α-hydrazino esters by α-hydrazination of 3-oxoindolines using azodicarboxylate via aza-Michael reaction.
General description:	Hydroquinidine, a cinchona alkaloid, is a structural analog of quinidine. It shows antiarrhythmic effect.
Packaging:	5 g in glass bottle

Symbol	GHS07
Signal word	Warning
Hazard statements	H302
Precautionary statements	P264 - P270 - P301 + P312 - P501
Hazard Codes	Xn
Risk Statements	20/21/22
Safety Statements	36/37
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Purity	95%
mp	169-170 °C (lit.)
UNSPSC	12352005

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