Acetyltrimethylsilane

ALDRICH/362824 - 97%

Synonym: 1-(Trimethylsilyl)ethanone

CAS Number: 13411-48-8
Empirical Formula (Hill Notation): C₅H₁₂OSi
Molecular Weight: 116.23
MDL Number: MFCD00134244
Linear Formula: (CH₃)₃SiCOCH₃
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-362824-5G	5 g	$169.00 1/EA		Add To Favorites
45-362824-25G	25 g	$591.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	97%
density	0.811 g/mL at 25 °C (lit.)
InChI	1S/C5H12OSi/c1-5(6)7(2,3)4/h1-4H3
InChI key	REDWSDBFBCDPNI-UHFFFAOYSA-N
refractive index	n20/D 1.411 (lit.)
SMILES string	CC(=O)[Si](C)(C)C
storage temp.	2-8°C

Application:	Acetyltrimethylsilane can be used as a reagent in the synthesis of dihydrophenanthrenes via a C-C insertion reaction. It is also used as a source of carbanion in the synthesis of unsymmetrical biaryls by carbanion-induced ring transformation of 2H-pyran-2-ones under mild basic conditions.
General description:	Acetyltrimethylsilane is an organosilicon compound that is commonly used as a protective agent for alcohols and amines in organic synthesis. It is also used as a reagent in various reactions, which includes trimethylsilylation, condensation, carbon-carbon bond formation, and reductive amination reactions.
Packaging:	5, 25 g in glass bottle

Symbol	GHS02,GHS07
Signal word	Danger
Hazard statements	H225 - H315 - H319 - H335
Precautionary statements	P210 - P302 + P352 - P305 + P351 + P338
Hazard Codes	F,Xi
Risk Statements	11-36/37/38
Safety Statements	16-26-36
RIDADR	UN 1993BF 3 / PGII
WGK Germany	WGK 3
Flash Point(F)	46.4 °F - closed cup
Flash Point(C)	8 °C - closed cup

Purity	97%
Density	0.811 g/mL at 25 °C (lit.)
Refractive Index	n20/D 1.411 (lit.)
Storage Temp.	2-8°C
UNSPSC	12352103

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