(Triphenylphosphine)copper hydride hexamer
ALDRICH/364975 - 90%
Synonym: Cuprous hydride triphenylphosphine hexamer; Hydrido(triphenylphosphine)
CAS Number: 33636-93-0
Empirical Formula (Hill Notation): C108H96Cu6P6
Molecular Weight: 1961.04
MDL Number: MFCD00221518
Linear Formula: [(C6H5)3PCuH]6
Product Type: Chemical
assay | 90% |
InChI | 1S/6C18H15P.6Cu.6H/c6*1-4 |
InChI key | PYHLOCIDGQNZFY-UHFFFAOYSA |
reaction suitability | reagent type: reductant |
SMILES string | [CuH].[CuH].[CuH].[CuH].[ |
Application: | Catalyst for: • Conjugate reduction of ortho-substituted cinnamic esters to form copper enolates • Chemoselective preparation of alcohols via hydrogenation of aldehydes • 1,2-addition/transmetal • Synthesis of monomer for preparation of phosphorus- and silicon-containing epoxy resins • Hydrosilylation reactions • Chiral hydrogenation reactions • Hydrostannation of activated alkynes |
Application: | Some useful synthetic applications of (Triphenylphosphine)coppe |
General description: | Triphenylgermanium hydride is a hydrogen donor. |
Packaging: | 1, 5 g in glass bottle |
Symbol | GHS02 |
Signal word | Warning |
Hazard statements | H228 |
Precautionary statements | P210 - P240 - P241 - P280 - P370 + P378 |
Hazard Codes | Xi |
Risk Statements | 36/37/38 |
Safety Statements | 26-36 |
RIDADR | NONH for all modes of transport |
WGK Germany | WGK 3 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Purity | 90% |
UNSPSC | 12352002 |