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(Triphenylphosphine)copper hydride hexamer

ALDRICH/364975 - 90%

Synonym: Cuprous hydride triphenylphosphine hexamer; Hydrido(triphenylphosphine)copper(I) hexamer; Stryker’s reagent; Triphenylphosphine–Copper(I) hydride Hexamer

CAS Number: 33636-93-0
Empirical Formula (Hill Notation): C108H96Cu6P6
Molecular Weight: 1961.04
MDL Number: MFCD00221518
Linear Formula: [(C6H5)3PCuH]6
Product Type: Chemical

Catalog Number PKG Qty. Price Quantity
45-364975-1G 1 g
$113.00
1/EA
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45-364975-5G 5 g
$323.00
1/EA
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This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 364975-1G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 364975-5G

 

assay 90%
InChI 1S/6C18H15P.6Cu.6H/c6*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;;;;;;;;;;/h6*1-15H;;;;;;;;;;;;
InChI key PYHLOCIDGQNZFY-UHFFFAOYSA-N
reaction suitability reagent type: reductant
SMILES string [CuH].[CuH].[CuH].[CuH].[CuH].[CuH].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9.c%10ccc(cc%10)P(c%11ccccc%11)c%12ccccc%12.c%13ccc(cc%13)P(c%14ccccc%14)c%15ccccc%15.c%16ccc(cc%16)P(c%17ccccc%17)c%18ccccc%18
Application: Catalyst for:
• Conjugate reduction of ortho-substituted cinnamic esters to form copper enolates
• Chemoselective preparation of alcohols via hydrogenation of aldehydes
• 1,2-addition/transmetalation reactions
• Synthesis of monomer for preparation of phosphorus- and silicon-containing epoxy resins
• Hydrosilylation reactions
• Chiral hydrogenation reactions
• Hydrostannation of activated alkynes
Application: Some useful synthetic applications of (Triphenylphosphine)copperhydride hexamer include stoichiometric and catalytic hydrogenations, chemoselective conjugate reductions, as well as regiospecific and stereoselectiveconjugate hydride reductions.
General description: Triphenylgermanium hydride is a hydrogen donor.
Packaging: 1, 5 g in glass bottle
Purity 90%
UNSPSC 12352002

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