Methyl α-bromophenylacetate

ALDRICH/365270 - 97%

CAS Number: 3042-81-7
Empirical Formula (Hill Notation): C₉H₉BrO₂
Molecular Weight: 229.07
MDL Number: MFCD00013535
Linear Formula: C₆H₅CH(Br)CO₂CH₃
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-365270-5G	5 g	$63.30 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	97%
bp	113 °C/3 mmHg (lit.)
density	1.455 g/mL at 25 °C (lit.)
form	liquid
InChI	1S/C9H9BrO2/c1-12-9(11)8(10)7-5-3-2-4-6-7/h2-6,8H,1H3
InChI key	NHFBYYMNJUMVOT-UHFFFAOYSA-N
refractive index	n20/D 1.553 (lit.)
SMILES string	COC(=O)C(Br)c1ccccc1
storage temp.	2-8°C

Application:	Methyl α-bromophenylacetate may be used as initiator during ESR study of atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) and ethylene glycol dimethacrylate (EGDMA). It may be used as reagent in the homopolymerization of MMA in supercritical carbon dioxide.
General description:	Methyl α-bromophenylacetate is an ester. Palladium catalyzed homocoupling reaction of methyl α-bromophenylacetate with 3,5-dimethyl phenyl boronic acid is reported.
Packaging:	5 g in glass bottle

Symbol	GHS05
Signal word	Danger
Hazard statements	H314
Precautionary statements	P280 - P305 + P351 + P338 - P310
Hazard Codes	C
Risk Statements	34
Safety Statements	26-36/37/39-45
RIDADR	UN 3265 8 / PGII
WGK Germany	WGK 3
Flash Point(F)	235.4 °F - closed cup
Flash Point(C)	113 °C - closed cup

Purity	97%
bp	113 °C/3 mmHg (lit.)
Density	1.455 g/mL at 25 °C (lit.)
Refractive Index	n20/D 1.553 (lit.)
Storage Temp.	2-8°C
UNSPSC	12352100

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