Methyl nitroacetate

ALDRICH/366463 - 98%

CAS Number: 2483-57-0
Empirical Formula (Hill Notation): C₃H₅NO₄
Molecular Weight: 119.08
EC Number: 219-622-0
MDL Number: MFCD00075480
Linear Formula: NO₂CH₂COOCH₃
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-366463-5G	5 g	$440.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	98%
bp	195-198 °C (lit.)
density	1.294 g/mL at 25 °C (lit.)
form	liquid
InChI	1S/C3H5NO4/c1-8-3(5)2-4(6)7/h2H2,1H3
InChI key	ALBSWLMUHHZLLR-UHFFFAOYSA-N
refractive index	n20/D 1.425 (lit.)
SMILES string	COC(=O)C[N+]([O-])=O

Application:	Methyl nitroacetate may be used: • in the preparation of aromatic and heteroaromatic linear (E)-α-nitro-arylpentenoates • to generate phenyliodonium ylide, used in the highly enantioselective and diastereoselective Cu(I)-catalyzed cyclopropanation of alkenes • in the preparation of methyl (Z)-2-nitro-3-(4-nitrophenyl)-2-propenoate, via reaction with 4-nitrobenzylideneaniline
Packaging:	1, 5 g in glass bottle

Symbol	GHS07
Signal word	Warning
Hazard statements	H315 - H319 - H335
Precautionary statements	P302 + P352 - P305 + P351 + P338
Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-36
RIDADR	NONH for all modes of transport
WGK Germany	WGK 2
Flash Point(F)	221.0 °F - closed cup
Flash Point(C)	105 °C - closed cup

Purity	98%
bp	195-198 °C (lit.)
Density	1.294 g/mL at 25 °C (lit.)
Refractive Index	n20/D 1.425 (lit.)
UNSPSC	12352100

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