Sodium trifluoromethanesulfonate
ALDRICH/367907 - 98%
Synonym: Sodium triflate; Trifluoromethanesulfonic acid sodium salt
CAS Number: 2926-30-9
Empirical Formula (Hill Notation): CF3NaO3S
Molecular Weight: 172.06
MDL Number: MFCD00061607
Linear Formula: CF3SO3Na
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 367907-25G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 367907-5G
| assay | 98% |
| form | solid |
| InChI | 1S/CHF3O3S.Na/c2-1(3,4)8( |
| InChI key | XGPOMXSYOKFBHS-UHFFFAOYSA |
| mp | 253-255 °C (lit.) |
| SMILES string | [Na+].[O-]S(=O)(=O)C(F)(F |
| Application: | Sodium trifluoromethanesulfonate can be employed as a reagent for the preparation of: • Aryl fluorides via silver-catalyzed fluorination of arylstannanes. • Ionic liquids such as N, N -dialkylpyrrolidinium triflate, N,N-dialkylimidazolium triflate, and N-alkylpyridinium triflate. It can be also used as supporting electrolyte in electrochemical O-glycosylation of primary alcohols with O-protected thioglycosides. |
| General description: | Sodium trifluoromethanesulfonate (Sodium triflate or NaOTf) is an efficient catalyst as well as a reagent in many organic reactions. The prominent application includes catalytic asymmetric Mannich-type reactions, Mannich-type reactions in water, and Diels-Alder reactions.It is also used as an electrolyte in batteries. |
| Packaging: | 5, 25 g in glass bottle |
| Symbol |  GHS07 |
| Signal word | Warning |
| Hazard statements | H315 - H319 - H335 |
| Precautionary statements | P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338 |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26-37/39 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 2 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | 98% |
| mp | 253-255 °C (lit.) |
| UNSPSC | 12352302 |