(Trimethylsilyl)methyl isocyanide
ALDRICH/376159 - 97%
Synonym: (Isocyanomethyl)
CAS Number: 30718-17-3
Empirical Formula (Hill Notation): C5H11NSi
Molecular Weight: 113.23
MDL Number: MFCD00043056
Linear Formula: (CH3)3SiCH2NC
Product Type: Chemical
| assay | 97% |
| bp | 52-53 °C/35 mmHg (lit.) |
| density | 0.803 g/mL at 25 °C (lit.) |
| form | liquid |
| InChI | 1S/C5H11NSi/c1-6-5-7(2,3) |
| InChI key | OLSTVZKPVGMQKB-UHFFFAOYSA |
| refractive index | n |
| SMILES string | C[Si](C)(C)C[N+]#[C-] |
| storage temp. | −20°C |
| Application: | (Trimethylsilyl)methyl isocyanide may be used in the preparation of isocyanomethylenetripheny |
| General description: | Synthesis of (trimethylsilyl)methyl isocyanide and its reaction with protic nucleophiles has been reported. An improved preparation of (trimethylsilyl)methyl isocyanide is reported. Reaction of (trimethylsilyl)methyl isocyanide with (η2-formaldehyde)zirconocene complex is reported to yield insertion products. |
| Packaging: | 500 mg in amber glass bottle |
| Packaging: | Bottomless glass bottle. Contents are inside inserted fused cone. |
| Symbol |   GHS02,GHS06 |
| Signal word | Danger |
| Hazard statements | H225 - H301 + H311 + H331 |
| Precautionary statements | P210 - P233 - P280 - P301 + P310 - P303 + P361 + P353 - P304 + P340 + P311 |
| Hazard Codes | F,T |
| Risk Statements | 11-23/24/25 |
| Safety Statements | 16-36/37/39-45 |
| RIDADR | UN 1993C 3 / PGIII |
| WGK Germany | WGK 3 |
| Flash Point(F) | < 59.0 °F - closed cup |
| Flash Point(C) | < 15 °C - closed cup |
| Purity | 97% |
| bp | 52-53 °C/35 mmHg (lit.) |
| Density | 0.803 g/mL at 25 °C (lit.) |
| Refractive Index | n |
| Storage Temp. | −20°C |
| UNSPSC | 12352100 |