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2,3,5,6-Tetrafluoro-7,7,8,8-tetracyanoquinodimethane

ALDRICH/376779 - 97%

Synonym: (2,3,5,6-Tetrafluoro-2,5-cyclohexadiene-1,4-diylidene)dimalononitrile; 7,7,8,8-Tetracyano-2,3,5,6-tetrafluoroquinodimethane; F4TCNQ

CAS Number: 29261-33-4
Empirical Formula (Hill Notation): C12F4N4
Molecular Weight: 276.15
MDL Number: MFCD00042382
Linear Formula: C12F4N4
Product Type: Chemical

Catalog Number PKG Qty. Price Quantity
45-376779-25MG 25 mg
$110.00
1/EA
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45-376779-100MG 100 mg
$315.00
1/EA
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assay 97%
form solid
InChI 1S/C12F4N4/c13-9-7(5(1-17)2-18)10(14)12(16)8(11(9)15)6(3-19)4-20
InChI key IXHWGNYCZPISET-UHFFFAOYSA-N
mp 285-290 °C (lit.)
SMILES string FC1=C(F)C(C(F)=C(F)/C1=C(C#N)C#N)=C(C#N)C#N
Application: F4-TCNQ can be doped with poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine] (PTAA) to form a hole transport material (HTL), which can be used to achieve an energy efficiency of 16% for a semi-transparent perovskite solar cell. It can be used as a p-type dopant to form a blended composite film with poly(3-hexylthiophene) (P3HT) having enhanced charge mobility, which can be potentially useful in organic photovoltaics.
Application: F4-TCNQ is the p-type dopant for hole-only devices and field effect transistors with organic hole transport layers (HTL). It is used in the preparation of a bilayer structure of F4-TCNQ and pentacene to study improved thermoelectric performance of organic thin films.
General description: 2,3,5,6-Tetrafluoro-7,7,8,8-tetracyanoquinodimethane (F4-TCNQ) is a dopant used in the fabrication of organic semiconductors. It can tune the electronic properties as its lowest unoccupied molecular orbital is at a desirable energy level required to oxidize a wide range of semiconductors.
General description: 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane (F4-TCNQ) are p-type molecules, used as a strong acceptor dopant , it generates free holes.
Packaging: 25, 100 mg in glass insert
Purity 97%
mp 285-290 °C (lit.)
UNSPSC 12352103

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