N-Methoxy-N-methyl(triphenylphosphoranylidene)acetamide
ALDRICH/376876 - 98%
Synonym: (N-
CAS Number: 129986-67-0
Empirical Formula (Hill Notation): C22H22NO2P
Molecular Weight: 363.39
MDL Number: MFCD00134433
Linear Formula: (C6H5)3P=CHCON(OCH3)CH3
Product Type: Chemical
assay | 98% |
InChI | 1S/C22H22NO2P/c1-23(25-2) |
InChI key | DGBLSOOPDBHHRX-UHFFFAOYSA |
mp | 173-175 °C (lit.) |
reaction suitability | reaction type: C-C Bond Formation |
SMILES string | CON(C)C(=O)C=P(c1ccccc1)( |
Application: | Reactant for: • Synthesis of electron-deficient alkenes via stereoselective olefination of N-sulfonyl imines • Phosphine-catalyzed asymmetric addition reactions • Cysteine-catalyzed enantioselective intramolecular Rauhut-Currier reaction • Wittig olefination • Synthesis of aigialomycin D, a Protein Kinase inhibitor and a potential anticancer agent |
Packaging: | 5, 25 g in glass bottle |
Symbol | GHS07 |
Signal word | Warning |
Hazard statements | H315 - H319 - H335 |
Precautionary statements | P302 + P352 - P305 + P351 + P338 |
Hazard Codes | Xi |
Risk Statements | 36/37/38 |
Safety Statements | 26-36 |
RIDADR | NONH for all modes of transport |
WGK Germany | WGK 3 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Purity | 98% |
mp | 173-175 °C (lit.) |
UNSPSC | 12352002 |