Chlorobis(cyclooctene)iridium(I)dimer

ALDRICH/377155 - 97%

Synonym: [Ir(coe)₂Cl]₂; Di-μ-chlorotetrakis(cyclooctene)diiridium

CAS Number: 12246-51-4
Empirical Formula (Hill Notation): C₃₂H₅₆Cl₂Ir₂
Molecular Weight: 896.13
MDL Number: MFCD00213465
Linear Formula: C₃₂H₅₆Cl₂Ir₂
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-377155-250MG	250 mg	$158.00 1/EA		Add To Favorites
45-377155-1G	1 g	$603.00 1/EA		Add To Favorites
45-377155-5G	5 g	$1970.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	97%
form	powder
InChI	1S/4C8H14.2ClH.2Ir/c41-2-4-6-8-7-5-3-1;;;;/h41-2H,3-8H2;21H;;/q;;;;;;2+1/p-2/b4*2-1-;;;;
InChI key	WBRREXQCZAFSKS-XFCUKONHSA-L
mp	160-165 °C (dec.) (lit.)
reaction suitability	core: iridium
	reagent type: catalyst
SMILES string	Cl[Ir].Cl[Ir].[CH]1[CH]CCCCCC1.[CH]2[CH]CCCCCC2.[CH]3[CH]CCCCCC3.[CH]4[CH]CCCCCC4

Application:	Catalyst for: • Isomerization-hydroboration reactions with nido-carboranyldiphosphine as stabilizing ligand • Hydrogen peroxide oxidation of hydroxamic acids and their subsequent hetero Diels-Alder cycloaddition reactions • Immobilization of organic functional groups onto solid supports through vinylsilane coupling reactions • Alkylation reactions • Guerbet reaction • Allylic amination reactions in a DNA-diene-iridium(I) hybrid system • Asymmetric hydroamination reactions
Application:	Chlorobis(cyclooctene)iridium(I)dimer can be used as a catalyst for: • Isomerization-hydroboration reactions with nido-carboranyldiphosphine as stabilizing ligand. • Hydrogen peroxide oxidation of hydroxamic acids and their subsequent hetero Diels-Alder cycloaddition reactions. • Immobilization of organic functional groups onto solid supports through vinylsilane coupling reactions. • Alkylation reactions. • Guerbet reaction. • Allylic amination reactions using a DNA-diene-iridium(I) hybrid system. • Asymmetric hydroamination reactions.
Packaging:	1, 5 g in glass bottle
Packaging:	250 mg in glass bottle

Symbol	GHS07
Signal word	Warning
Hazard statements	H315 - H319 - H335
Precautionary statements	P302 + P352 - P305 + P351 + P338
Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-37/39
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Purity	97%
mp	160-165 °C (dec.) (lit.)
UNSPSC	12161600

Choose a favorite list for this item:

Catalog Number	Description	Price

		$

Please choose a list :

Continue Shopping

Returns/Order support

Please fill out the form below if you want to request order support from Krackeler Scientific.