(S)-(+)-Citronellyl bromide
ALDRICH/377716 - 95%
Synonym: 8-
CAS Number: 143615-81-0
Empirical Formula (Hill Notation): C10H19Br
Molecular Weight: 219.16
MDL Number: MFCD00134459
Linear Formula: (CH3)2C=CHCH2CH2CH(CH3)CH2CH2Br
Product Type: Chemical
| assay | 95% |
| bp | 111 °C/12 mmHg (lit.) |
| density | 1.11 g/mL at 25 °C (lit.) |
| form | liquid |
| InChI | 1S/C10H19Br/c1-9(2)5-4-6- |
| InChI key | QPKCDMXLSDFCQD-JTQLQIEISA |
| optical activity | [α]20/D +6.8°, neat |
| refractive index | n |
| SMILES string | C[C@H](CCBr)CCC=C(C)C |
| Application: | (S)-(+)-Citronellyl bromide can be used as a reactant in the Negishi cross-coupling reaction. It is also used in the synthesis of spiroacetal parts of spirofungin A and B by reacting with epoxy alcohol via alkyne–lactone coupling reaction and diastereomeric separation. |
| General description: | (S)-(+)-Citronellyl bromide is a chiral organic compound that is commonly used as a reagent in organic synthesis to prepare chiral building blocks with the citronellyl group, which is used in various organic syntheses. It can also be used in the formation of chiral catalysts, which are useful in the synthesis of enantiomerically pure compounds. |
| Packaging: | 5, 25 g in glass bottle |
| Symbol |  GHS07 |
| Signal word | Warning |
| Hazard statements | H315 - H319 - H335 |
| Precautionary statements | P302 + P352 - P305 + P351 + P338 |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26-37/39 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 3 |
| Flash Point(F) | 203.0 °F - closed cup |
| Flash Point(C) | 95 °C - closed cup |
| Purity | 95% |
| bp | 111 °C/12 mmHg (lit.) |
| Density | 1.11 g/mL at 25 °C (lit.) |
| Refractive Index | n |
| UNSPSC | 12352101 |