1-(Triisopropylsilyl)pyrrole

ALDRICH/377945 - 95%

CAS Number: 87630-35-1
Empirical Formula (Hill Notation): C₁₃H₂₅NSi
Molecular Weight: 223.43
MDL Number: MFCD00054932
Linear Formula: C₁₃H₂₅NSi
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-377945-5ML	5 mL	$0.00 1/EA CALL FOR PRICE		Add To Favorites
45-377945-25ML	25 mL	$206.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	95%
bp	78 °C/0.4 mmHg (lit.)
density	0.904 g/mL at 25 °C (lit.)
form	liquid
InChI	1S/C13H25NSi/c1-11(2)15(12(3)4,13(5)6)14-9-7-8-10-14/h7-13H,1-6H3
InChI key	FBQURXLBJJNDBX-UHFFFAOYSA-N
refractive index	n20/D 1.492 (lit.)
SMILES string	CC(C)[Si](C(C)C)(C(C)C)n1cccc1

Application:	1-(Triisopropylsilyl)pyrrole may be employed as reagent in perfluoroalkylation and Vilsmeier formylation reactions. It may be used in the preparation of: • ethyl 2-(2,4-dinitrophenylhydrazono]-3-[ 1-(triisopropylsily1)-pyrrol-2-yflpropanoate • heterocyclic base, 3-nitropyrrole • 3-nitropyrrole, required for the synthesis of 1 -(2′-deoxy-β-D-ribofuranosyl)-3-nitropyrrole
General description:	1-(Triisopropylsilyl)pyrrole (TISP), a heterocyclic building block, is a pyrrole derivative. TISP has been reported to generate pyrrolic cation radicals during cyclovoltammetric studies, via electroreduction. It participates in various electrophilic substitution reactions specifically at β-position, via reaction with various electrophilic reagents (Br⁺, I⁺,NO₂⁺,etc).
Packaging:	5, 25 mL in glass bottle

Symbol	GHS07
Signal word	Warning
Hazard statements	H302 + H332 - H319
Precautionary statements	P301 + P312 + P330 - P304 + P340 + P312 - P305 + P351 + P338
Hazard Codes	Xn
Risk Statements	20-22-36
Safety Statements	26
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	224.6 °F - closed cup
Flash Point(C)	107 °C - closed cup

Purity	95%
bp	78 °C/0.4 mmHg (lit.)
Density	0.904 g/mL at 25 °C (lit.)
Refractive Index	n20/D 1.492 (lit.)
UNSPSC	12352100

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