Potassium diphenylphosphide solution

ALDRICH/380768 - 0.5 M in THF

Synonym: Potassium diphenylphosphine; Diphenylphosphine potassium salt; KPPh₂

CAS Number: 15475-27-1
Empirical Formula (Hill Notation): C₁₂H₁₀KP
Molecular Weight: 224.28
MDL Number: MFCD00134530
Linear Formula: (C₆H₅)₂PK
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-380768-100ML	100 mL	$151.00 1/EA	Add To Favorites
45-380768-800ML	800 mL	$735.00 1/EA	Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

concentration	0.5 M in THF
density	0.929 g/mL at 25 °C
form	liquid
functional group	phosphine
InChI	1S/C12H10P.K/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10H;/q-1;+1
InChI key	FCLYZQXPJKJTDR-UHFFFAOYSA-N
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction
	reaction type: Heck Reaction
	reaction type: Hiyama Coupling
	reaction type: Negishi Coupling
	reaction type: Sonogashira Coupling
	reaction type: Stille Coupling
	reaction type: Suzuki-Miyaura Coupling
	reagent type: ligand
SMILES string	[K]P(c1ccccc1)c2ccccc2

Application:

Synthesis, reactivity and molecular structure of phosphino tetramethyl cyclopentadienyl complex (eta5: eta1-C5Me4CH2PPh2)Re(CO)2.: This study explores the synthesis and reactivity of a novel phosphino complex, utilizing Potassium diphenylphosphide as a key reagent. The research highlights the molecular structure and potential applications in organometallic chemistry (Godoy et al., 2009 ).

Improved and efficient synthesis of chiral N,P-ligands via cyclic sulfamidates for asymmetric addition of butyllithium to benzaldehyde.: This paper details an improved synthesis method for chiral N,P-ligands using Potassium diphenylphosphide. The research demonstrates the compound′s efficacy in asymmetric synthesis, offering potential advancements in drug discovery and development (Rönnholm et al., 2007 ).

Coordination chemistry of diselenophosphinate complexes: the X-ray single-crystal structures of [K(Se2PPh2)(THF)2]2 and [In(Se2PPh2)3].L (L = THF, PhMe).: This article investigates the coordination chemistry involving diselenophosphinate complexes, with Potassium diphenylphosphide playing a crucial role. The study provides detailed X-ray crystallographic data, offering insights for future research in chemical synthesis and materials science (Davies et al., 2004 ).

Packaging:

100, 800 mL in Sure/Seal™

Symbol	GHS02,GHS05,GHS07,GHS08
Signal word	Danger
Hazard statements	H225 - H302 - H314 - H335 - H351
Precautionary statements	P201 - P210 - P233 - P280 - P303 + P361 + P353 - P305 + P351 + P338
Hazard Codes	F,C
Risk Statements	11-19-34-37-40
Safety Statements	16-26-36/37/39-45
RIDADR	UN 2924 8(3) / PGII
WGK Germany	WGK 3
Flash Point(F)	-4.0 °F - closed cup
Flash Point(C)	-20 °C - closed cup
Supplemental Hazard Statements	EUH018 - EUH019

Density	0.929 g/mL at 25 °C
UNSPSC	12352002

To Order From a Quote