tert-Butyldichlorophosphine
ALDRICH/381020 - 98%
Synonym: tert-Butylphosphine dichloride; tert-
CAS Number: 25979-07-1
Empirical Formula (Hill Notation): C4H9Cl2P
Molecular Weight: 158.99
EC Number: 247-386-9
MDL Number: MFCD00013615
Linear Formula: (CH3)3CPCl2
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 381020-10G
| assay | 98% |
| functional group | phosphine |
| InChI | 1S/C4H9Cl2P/c1-4(2,3)7(5) |
| InChI key | NMJASRUOIRRDSX-UHFFFAOYSA |
| mp | 44-49 °C (lit.) |
| reaction suitability | reaction type: Buchwald-Hartwig Cross Coupling Reaction |
| reaction type: Heck Reaction | |
| reaction type: Hiyama Coupling | |
| reaction type: Negishi Coupling | |
| reaction type: Sonogashira Coupling | |
| reaction type: Stille Coupling | |
| reaction type: Suzuki-Miyaura Coupling | |
| SMILES string | CC(C)(C)P(Cl)Cl |
| Application: | tert-Butyldichlorophosphine can be used as a reactant for the synthesis of: • Dihydrobenzooxaphosphol • tert-Butyl functionalized 1,3-C6H4(CH2PR2)2 (PCP) pincer ligands. • Chloro-phosphinite reagent by reacting with sodium ethoxide. • 2-(tert-Butylhydrophosphoryl)-1-phenyl-1H-imidazole derivatives. |
| Packaging: | 10 g in glass bottle |
| Symbol |  GHS05 |
| Signal word | Danger |
| Hazard statements | H314 |
| Precautionary statements | P260 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P305 + P351 + P338 |
| Hazard Codes | C |
| Risk Statements | 14-34 |
| Safety Statements | 26-27-28-36/37/39-45 |
| RIDADR | UN 3261 8 / PGII |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Supplemental Hazard Statements | EUH014 |
| Purity | 98% |
| mp | 44-49 °C (lit.) |
| UNSPSC | 12352001 |