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Cerium(III) acetylacetonate hydrate

ALDRICH/381403

Synonym: Ce(acac)3; Cerium(III) 2,4-pentanedionate

CAS Number: 206996-61-4
Empirical Formula (Hill Notation): C15H21CeO6 · xH2O
Molecular Weight: 437.44 (anhydrous basis)
EC Number: 239-720-7
MDL Number: MFCD00150164
Linear Formula: Ce(C5H7O2)3 · xH2O
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-381403-50G 50 g
 $250.00
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composition Ce, ≥20% complexometric
form crystalline powder
InChI 1S/3C5H8O2.Ce.H2O/c3*1-4(6)3-5(2)7;;/h3*3,6H,1-2H3;;1H2/q;;;+3;/p-3/b3*4-3-;;
InChI key KGJWXERBZWXYFB-KJVLTGTBSA-K
Quality Level 200 
reaction suitability core: cerium
  reagent type: catalyst
SMILES string O.CC(=O)C=C(C)O[Ce](OC(C)=C/C(C)=O)OC(C)=C/C(C)=O
Application: Cerium(III) acetylacetonate hydrate can be used as: • A precursor to synthesize ceria (CeO₂) nanopowders via the sol-gel process.
• A dopant precursor during the solvothermal synthesis of zinc oxide (ZnO) nanopowder to modify the structural and optical properties of the nanopowder.
• A precursor to synthesize gadolinia-doped ceria (GDC) via sol-gel synthesis.
Features and Benefits: • Thermally stable compound
• Soluble in various solvents
• Exhibits redox properties due to the Ce(III)/Ce(IV) couple, enabling participation in oxidation-reduction reactions
General description: Cerium(III) acetylacetonate is a crystalline powder used as an inorganic catalyst and as a precursor in solution and vapor deposition processes. It is valued for its redox-active cerium center, making it useful in catalytic applications and the fabrication of thin films and advanced materials. It is soluble in organic solvents, forms stable chelate complexes, and is valuable in applications such as the synthesis of nanostructured materials, glass polishing, and as a reagent in organic synthesis.
Packaging: 250 g in glass bottle
Packaging: 50 g in poly bottle
UNSPSC 12352103

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