Nysted Reagent
ALDRICH/381985 - 20 wt. % suspension in THF
Synonym: cyclo-Dibromodi-μ-methylene[μ-(tetrahydrofuran)]trizinc
CAS Number: 41114-59-4
Empirical Formula (Hill Notation): C6H12Br2OZn3
Molecular Weight: 456.14
MDL Number: MFCD00134567
Linear Formula: C6H12Br2OZn3
Product Type: Chemical
| concentration | 20 wt. % suspension in THF |
| density | 1.186 g/mL at 25 °C (lit.) |
| form | slurry |
| functional group | ether |
| InChI | 1S/C4H8O.2CH2.2BrH.3Zn/c1 |
| InChI key | CCTHTLJWXPUNGT-UHFFFAOYSA |
| Quality Level | 200 ![]() |
| reaction suitability | reaction type: C-C Bond Formation |
| SMILES string | C1CCOC1.Br[Zn]C[Zn]C[Zn]B |
| Application: | Reactant for: • Synthesis of amphidinolide T3 using a ring-closing metathesis and asymmetric dihydroxylation strategy • Methylenation of carbonyl compounds • Olefination reactions |
| Application: | Useful reagent for the methylenation of ketones and α-ketols. |
| Packaging: | 1 kg in glass bottle |
| Packaging: | 100 g in glass bottle |
| Symbol | ![]() ![]() GHS02,GHS07,GHS08 |
| Signal word | Danger |
| Hazard statements | H225 - H319 - H335 - H336 - H351 |
| Precautionary statements | P201 - P202 - P210 - P233 - P305 + P351 + P338 - P308 + P313 |
| Hazard Codes | F,Xn |
| Risk Statements | 11-19-36/37-40 |
| Safety Statements | 16-26-36/37 |
| RIDADR | UN 3399BC 4.3(3) / PGII |
| WGK Germany | WGK 3 |
| Flash Point(F) | -14.8 °F |
| Flash Point(C) | -26 °C |
| Supplemental Hazard Statements | EUH019 |
| Density | 1.186 g/mL at 25 °C (lit.) |
| UNSPSC | 12352005 |




